Synthesis of Nickel Hexacyanoferrate Nanoparticles and Their Potential as Heterogeneous Catalysts for the Solvent-Free Oxidation of Benzyl Alcohol

doi:10.1016/S1872-2067(10)60292-6

催化学报 ›› 2011, Vol. 32 ›› Issue (12): 1844-1849.DOI: 10.1016/S1872-2067(10)60292-6

Synthesis of Nickel Hexacyanoferrate Nanoparticles and Their Potential as Heterogeneous Catalysts for the Solvent-Free Oxidation of Benzyl Alcohol

Shah R. ALI1,*, Prakash CHANDRA1, Mamta LATWAL1, Shalabh K. JAIN2, Vipin K. BANSAL3,4, Sudhanshu P. SINGH3

1Department of Chemistry, Kumaun University, Nainital 263 002, Uttarakhand, India; 2Department of Chemistry, Gurukula Kangri University, Haridwar 249 404, Uttarakhand, India; 3Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247 667, Uttarakhand, India; 4Faculty of Chemistry, Department of Applied Science, Mangalayatan University, Aligarh 202145, Uttar Pradesh, India

收稿日期:2011-07-21 修回日期:2011-09-27 出版日期:2011-12-21 发布日期:2015-04-23

Synthesis of Nickel Hexacyanoferrate Nanoparticles and Their Potential as Heterogeneous Catalysts for the Solvent-Free Oxidation of Benzyl Alcohol

Shah R. ALI1,*, Prakash CHANDRA1, Mamta LATWAL1, Shalabh K. JAIN2, Vipin K. BANSAL3,4, Sudhanshu P. SINGH3

1Department of Chemistry, Kumaun University, Nainital 263 002, Uttarakhand, India; 2Department of Chemistry, Gurukula Kangri University, Haridwar 249 404, Uttarakhand, India; 3Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee 247 667, Uttarakhand, India; 4Faculty of Chemistry, Department of Applied Science, Mangalayatan University, Aligarh 202145, Uttar Pradesh, India

Received:2011-07-21 Revised:2011-09-27 Online:2011-12-21 Published:2015-04-23

摘要/Abstract

摘要： Nickel hexacyanoferrate nanoparticles were synthesized and characterized using elemental analysis, thermal analysis, infrared spectroscopy, and X-ray diffraction. A FE-SEM image of the nickel hexacyanoferrate showed that it consists of nearly spherical particles with sizes ranging from 30 to 70 nm. The synthesized material was found to be a heterogeneous catalyst useful for the solvent-free oxidation of benzyl alcohol with H₂O₂ as an oxidant. A 36% conversion of benzyl alcohol to benzaldehyde was achieved under optimized reaction conditions using specific parameters such as the amount of catalyst, the temperature, the benzyl alcohol to H₂O₂ molar ratio, and the reaction time.

关键词: hexacyanoferrate nanoparticle, heterogeneous catalyst, benzyl alcohol, benzaldehyde

Abstract: Nickel hexacyanoferrate nanoparticles were synthesized and characterized using elemental analysis, thermal analysis, infrared spectroscopy, and X-ray diffraction. A FE-SEM image of the nickel hexacyanoferrate showed that it consists of nearly spherical particles with sizes ranging from 30 to 70 nm. The synthesized material was found to be a heterogeneous catalyst useful for the solvent-free oxidation of benzyl alcohol with H₂O₂ as an oxidant. A 36% conversion of benzyl alcohol to benzaldehyde was achieved under optimized reaction conditions using specific parameters such as the amount of catalyst, the temperature, the benzyl alcohol to H₂O₂ molar ratio, and the reaction time.

Key words: hexacyanoferrate nanoparticle, heterogeneous catalyst, benzyl alcohol, benzaldehyde

Shah R. ALI, Prakash CHANDRA, Mamta LATWAL, Shalabh K. JAIN, Vipin K. BANSAL, Sudhanshu P. SINGH. Synthesis of Nickel Hexacyanoferrate Nanoparticles and Their Potential as Heterogeneous Catalysts for the Solvent-Free Oxidation of Benzyl Alcohol[J]. 催化学报, 2011, 32(12): 1844-1849.

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Synthesis of Nickel Hexacyanoferrate Nanoparticles and Their Potential as Heterogeneous Catalysts for the Solvent-Free Oxidation of Benzyl Alcohol

Synthesis of Nickel Hexacyanoferrate Nanoparticles and Their Potential as Heterogeneous Catalysts for the Solvent-Free Oxidation of Benzyl Alcohol

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