Aerobic Oxidation of Alcohols to Carbonyl Compounds Catalyzed by Fe(NO3)3/4-OH-TEMPO under Mild Conditions

Abstract

Abstract: An efficient, inexpensive, and mild transition-metal oxidation protocol has bee n developed for the Fe(NO3)3/4-OH-TEMPO-catalyzed aerobic selective oxida tion of a wide range of primary and secondary alcohols, which may bear carbon- carbon double bond or O or N or S as heteroatoms, to the corresponding aldehydes and ketones.

Key words: alcohol, selective oxidation, air, 4-hydroxy-2, 2, 6, 6-tetramethyl-piperidyl-1-oxy, ferric nitrate nonahydrate

WANG Xinliang;LIANG Xinmiao*. Aerobic Oxidation of Alcohols to Carbonyl Compounds Catalyzed by Fe(NO3)3/4-OH-TEMPO under Mild Conditions[J]. Chinese Journal of Catalysis, 2008, 29(9): 935-939.

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Aerobic Oxidation of Alcohols to Carbonyl Compounds Catalyzed by Fe(NO3)3/4-OH-TEMPO under Mild Conditions

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