Chinese Journal of Catalysis ›› 2006, Vol. 27 ›› Issue (3): 255-258.

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Nanometer β Zeolite Made from Mesoporous Zeolite and Its Hydrocracking Performance

CHEN Song1,2*, XU Jie1, YANG Yongrong1, WANG Jingdai1, ZHANG Xiaoping2, ZHANG Kuixi2   

  1. 1 UNILAB Research Centre of Chemical Reaction Engineering, Zhejiang University, Hangzhou 312000, Zhejiang, China; 2 Fushun Research Institute of Petroleum and Petrochemicals, SINOPEC, Fushun 113001, Liaoning, China
  • Received:2006-03-25 Online:2006-03-25 Published:1984-10-26

Abstract: MCM-41, a typical mesoporous molecular sieve, was used as silicon source to synthesize β zeolite in hydrothermal process. The β zeolite not only has all characteristics of a microporous zeolite but also inherits some properties of a mesoporous molecular sieve. Its pore diameter and pore volume are 30% and 60%, respectively, higher than that of the β zeolite prepared by the traditional method. Moreover it has smaller crystal grains and much more B acidity. Therefore, when being used as the cracking component in a hydrocracking catalyst, it shows improved catalytic performance. The dynamic activity is promoted by 60% and the middle distillate selectivity is significantly increased by 2.5% compared with the typical commercial hydrocracking catalyst.

Key words: &beta, zeolite, mesoporous zeolite, hydrothermal synthesis, hydrocracking catalyst