Preparation and Catalytic Performance of Cr2O3-ZnO Catalyst for Methanol Steam Reforming

Abstract

Abstract: The Cr2O3-ZnO catalyst for methanol steam reforming was prepared by the co-precipitation method and characterized by means of X-ray diffraction and N2 adsorption. The catalytic performance for methanol steam reforming was evaluated using a stainless steel microchannel reactor. The addition of Cr to ZnO resulted in the formation of ZnCr2O4 spinel and promoted the activity and stability of the catalysts, although the BET surface area decreased. However, raising the Cr content also led to an increase in the CO selectivity. The Cr2O3-ZnO catalysts with the Cr content of 5.3%[KG-45x]-[KG-20x]17.6% calcined at above 500 ℃ exhibited better catalytic performance than that calcined at 400 ℃.

Key words: methanol, steam reforming, zinc oxide, chromium oxide, hydrogen, microreactor

CAO Weiqiang, CHEN Guangwen*, CHU Jiansheng, LI Shulian, YUAN Quan. Preparation and Catalytic Performance of Cr2O3-ZnO Catalyst for Methanol Steam Reforming[J]. Chinese Journal of Catalysis, 2006, 27(10): 895-898.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/

https://www.cjcatal.com/EN/Y2006/V27/I10/895

[1]	Xiaolong Tang, Feng Li, Fang Li, Yanbin Jiang, Changlin Yu. Single-atom catalysts for the photocatalytic and electrocatalytic synthesis of hydrogen peroxide [J]. Chinese Journal of Catalysis, 2023, 52(9): 79-98.
[2]	Jiachen Sun, Sai Chen, Donglong Fu, Wei Wang, Xianhui Wang, Guodong Sun, Chunlei Pei, Zhi-Jian Zhao, Jinlong Gong. Role of oxygen transfer and surface reaction in catalytic performance of VO_x-Ce_1‒_xZr_xO₂ for propane dehydrogenation [J]. Chinese Journal of Catalysis, 2023, 52(9): 217-227.
[3]	Sikai Wang, Xiang-Ting Min, Botao Qiao, Ning Yan, Tao Zhang. Single-atom catalysts: In search of the holy grails in catalysis [J]. Chinese Journal of Catalysis, 2023, 52(9): 1-13.
[4]	Zicong Jiang, Bei Cheng, Liuyang Zhang, Zhenyi Zhang, Chuanbiao Bie. A review on ZnO-based S-scheme heterojunction photocatalysts [J]. Chinese Journal of Catalysis, 2023, 52(9): 32-49.
[5]	Xin Liu, Maodi Wang, Yiqi Ren, Jiali Liu, Huicong Dai, Qihua Yang. Construction of modularized catalytic system for transfer hydrogenation: Promotion effect of hydrogen bonds [J]. Chinese Journal of Catalysis, 2023, 52(9): 207-216.
[6]	Bowen Liu, Jiajie Cai, Jianjun Zhang, Haiyan Tan, Bei Cheng, Jingsan Xu. Simultaneous benzyl alcohol oxidation and H₂ generation over MOF/CdS S-scheme photocatalysts and mechanism study [J]. Chinese Journal of Catalysis, 2023, 51(8): 204-215.
[7]	Wei Qiao, Lice Yu, Jinfa Chang, Fulin Yang, Ligang Feng. Efficient bi-functional catalysis of coupled MoSe₂ nanosheet/Pt nanoparticles for methanol-assisted water splitting [J]. Chinese Journal of Catalysis, 2023, 51(8): 113-123.
[8]	Xiao-Juan Li, Ming-Yu Qi, Jing-Yu Li, Chang-Long Tan, Zi-Rong Tang, Yi-Jun Xu. Visible light-driven dehydrocoupling of thiols to disulfides and H₂ evolution over PdS-decorated ZnIn₂S₄ composites [J]. Chinese Journal of Catalysis, 2023, 51(8): 55-65.
[9]	Xiaohan Wang, Han Tian, Xu Yu, Lisong Chen, Xiangzhi Cui, Jianlin Shi. Advances and insights in amorphous electrocatalyst towards water splitting [J]. Chinese Journal of Catalysis, 2023, 51(8): 5-48.
[10]	Lu Cheng, Xuning Chen, P. Hu, Xiao-Ming Cao. Advantages and limitations of hydrogen peroxide for direct oxidation of methane to methanol at mono-copper active sites in Cu-exchanged zeolites [J]. Chinese Journal of Catalysis, 2023, 51(8): 135-144.
[11]	Ce Han, Bingbao Mei, Qinghua Zhang, Huimin Zhang, Pengfei Yao, Ping Song, Xue Gong, Peixin Cui, Zheng Jiang, Lin Gu, Weilin Xu. Atomic Ru coordinated by channel ammonia in V-doped tungsten bronze for highly efficient hydrogen-evolution reaction [J]. Chinese Journal of Catalysis, 2023, 51(8): 80-89.
[12]	Haifeng Liu, Xiang Huang, Jiazang Chen. Surface electronic state modulation promotes photoinduced aggregation and oxidation of trace CO for lossless purification of H₂ stream [J]. Chinese Journal of Catalysis, 2023, 51(8): 49-54.
[13]	Zhihan Yu, Chen Guan, Xiaoyang Yue, Quanjun Xiang. Infiltration of C-ring into crystalline carbon nitride S-scheme homojunction for photocatalytic hydrogen evolution [J]. Chinese Journal of Catalysis, 2023, 50(7): 361-371.
[14]	Bo Zhou, Jianqiao Shi, Yimin Jiang, Lei Xiao, Yuxuan Lu, Fan Dong, Chen Chen, Tehua Wang, Shuangyin Wang, Yuqin Zou. Enhanced dehydrogenation kinetics for ascorbic acid electrooxidation with ultra-low cell voltage and large current density [J]. Chinese Journal of Catalysis, 2023, 50(7): 372-380.
[15]	Bin Chen, Ya-Fei Jiang, Hai Xiao, Jun Li. Bimetallic single-cluster catalysts anchored on graphdiyne for alkaline hydrogen evolution reaction [J]. Chinese Journal of Catalysis, 2023, 50(7): 306-313.

Preparation and Catalytic Performance of Cr2O3-ZnO Catalyst for Methanol Steam Reforming

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics