Chinese Journal of Catalysis ›› 2007, Vol. 28 ›› Issue (1): 67-72.

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Different Reaction Characteristics of Hydride Transfer and Hydrogen Transfer in Catalytic Cracking

GONG Jianhong*, LONG Jun, XU Youhao   

  1. Research Institute of Petroleum Processing, SINOPEC, Beijing 100083, China
  • Received:2007-01-25 Online:2007-01-25 Published:2010-08-28

Abstract: Based on the Daqing vacuum gas oil’s reaction on an acid Y zeolite catalyst, hydride transfer and hydrogen transfer were distinguished as two different reaction stages during the catalytic cracking. Hydride transfer takes place at conversion intervals between 5%~10% and 60%~70%, while hydrogen transfer occurs at conversions above 60%~70%. Coke, independent of hydride transfer, is mainly produced by hydrogen transfer. The hydrogen transfer reaction on the Y zeolite catalyst mainly takes place between gasoline olefins and naphthenes.

Key words: vacuum gas oil, catalytic cracking, hydride transfer, hydrogen transfer