Coupling of Epoxides with Carbon Dioxide Catalyzed by Ruthenium Porphyrin

Abstract

Abstract: The coupling reaction of epoxides with carbon dioxide catalyzed by ruthenium porphyrin was studied. Reaction conditions were optimized. The new catalyst system of Ru(TPP)(PPh3)2/phenyltrimethylammonium tribromide (PTAT) promoted by ethyl diazoacetate (EDA) is very efficient to catalyze the coupling reaction of rious epoxides and CO2 at 323 K and the molar ratio of substrate∶catalyst∶EDA∶PTAT=200∶1∶1∶2.

Key words: ruthenium porphyrin complex, carbon dioxide, epoxide, coupling reaction, phenyltrimethyl-ammonium tribromide, ethyl diazoacetate

JIN Lili;CHANG Tao;JING Huanwang*. Coupling of Epoxides with Carbon Dioxide Catalyzed by Ruthenium Porphyrin[J]. Chinese Journal of Catalysis, 2007, 28(4): 287-289.

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https://www.cjcatal.com/EN/Y2007/V28/I4/287

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Coupling of Epoxides with Carbon Dioxide Catalyzed by Ruthenium Porphyrin

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