Chinese Journal of Catalysis ›› 2008, Vol. 29 ›› Issue (6): 503-505.

• Articles •     Next Articles

Selective Catalytic Reduction of NO with Propene over Au/Fe2O3/Al2O3 Catalysts

WANG Xinkui1,2*, ZHANG Wansheng2, WANG Aiqin2, WANG Xiaodong2, YANG Xuefeng1, ZHANG Tao2   

  1. 1 State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, Liaoning, China; 2 State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China
  • Received:2008-06-25 Online:2008-06-25 Published:2012-04-28

Abstract: A series of Au/Fe2O3/Al2O3 catalysts were prepared by the homogeneous deposition-precipitation method. The catalytic activity of the catalyst samples for selective catalytic reduction of NO by propene under oxygen-rich atmosphere was evaluated. The results showed that 2%Au/10%Fe2O3/Al2O3 exhibited good low-temperature activity. The maximum of NO conversion reached 43% at 300 ℃, while it was only 21% over 2%Au/Al2O3 catalyst at the same temperature. The addition of 2% steam to the feed gas had little effect on the catalytic activity.X-raydiffraction results indicated that both Au and Fe2O3 particles were highly dispersed over Al2O3. H2-temperature-programmed reduction results indicated that there was strong interaction between Au and Fe2O3, which made the reduction of Fe2O3 easy. The synergistic effect between Au and Fe2O3 was probably responsible for the good catalytic performance of the Au/Fe2O3/Al2O3 catalyst at low temperature.

Key words: gold nanoparticle, iron oxide, selective catalytic reduction, nitric oxide, propene