Microwave Synthesis of a&b-Oriented Zeolite T Membranes and Their Application in Pervaporation-Assisted Esterification

Chinese Journal of Catalysis ›› 2008, Vol. 29 ›› Issue (7): 592-594.

• Articles • Previous Articles Next Articles

Microwave Synthesis of a&b-Oriented Zeolite T Membranes and Their Application in Pervaporation-Assisted Esterification

ZHOU Han1,2, LI Yanshuo1, ZHU Guangqi1,2, LIU Jie1, LIN Liwu1, YANG Weishen1*

1 State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China; 2 Graduate University of Chinese Academy of Sciences, Beijing 100049, China

Received:2008-07-25 Online:2008-07-25 Published:2012-06-07

Abstract

Abstract: High-performance a&b-oriented zeolite T membranes were prepared by the microwave-assisted hydrothermal method. The membranes were applied to the pervaporation-assisted esterification of acetic acid and n-butyl alcohol at 383 K. Zeolite T membranes could effectively remove water product from the reactant mixtures and improve the conversion of acetic acid to 100% without the loss of reactants or products.

Key words: zeolite T, zeolite membrane, microwave synthesis, pervaporation, esterification

ZHOU Han;LI Yanshuo;ZHU Guangqi;LIU Jie;LIN Liwu;YANG Weishen*. Microwave Synthesis of a&b-Oriented Zeolite T Membranes and Their Application in Pervaporation-Assisted Esterification[J]. Chinese Journal of Catalysis, 2008, 29(7): 592-594.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/

https://www.cjcatal.com/EN/Y2008/V29/I7/592

[1]	Yuanyuan Jiang, Ruru Zhou, Huaiyuan Zhao, Boyong Ye, Yihua Long, Zhengbao Wang, Zhaoyin Hou. A highly active and stable organic-inorganic combined solid acid for the transesterification of glycerol under mild conditions [J]. Chinese Journal of Catalysis, 2021, 42(10): 1772-1781.
[2]	Juan Zhang, Yueying Chu, Xiaolong Liu, Hao Xu, Xiangju Meng, Zhaochi Feng, Feng-Shou Xiao. Interzeolite transformation from FAU to CHA and MFI zeolites monitored by UV Raman spectroscopy [J]. Chinese Journal of Catalysis, 2019, 40(12): 1854-1859.
[3]	Justina Gaidukevič, Jurgis Barkauskas, Anna Malaika, Paulina Rechnia-Gorący, Aleksandra Możdżyńska, Vitalija Jasulaitienė, Mieczysław Kozłowski. Modified graphene-based materials as effective catalysts for transesterification of rapeseed oil to biodiesel fuel [J]. Chinese Journal of Catalysis, 2018, 39(10): 1633-1645.
[4]	Na Huo, Hong Ma, Xinhong Wang, Tianlong Wang, Gang Wang, Ting Wang, Leilei Hou, Jin Gao, Jie Xu. High-efficiency oxidative esterification of furfural to methylfuroate with a non-precious metal Co-N-C/MgO catalyst [J]. Chinese Journal of Catalysis, 2017, 38(7): 1148-1154.
[5]	Yunhui Liao, Feng Li, Xin Dai, Ning Zhao, Fukui Xiao. Solid base catalysts derived from Ca-M-Al (M=Mg, La, Ce, Y) layered double hydroxides for dimethyl carbonate synthesis by transesterification of methanol with propylene carbonate [J]. Chinese Journal of Catalysis, 2017, 38(11): 1860-1869.
[6]	Xiaxia Bai, Liuyi Pan, Peng Zhao, Daidi Fan, Wenhong Li. A new solid acid SO₄^2-/TiO₂ catalyst modified with tin to synthesize 1,6-hexanediol diacrylate [J]. Chinese Journal of Catalysis, 2016, 37(9): 1469-1476.
[7]	Wei Xue, Hepan Zhao, Jie Yao, Fang Li, Yanji Wang . Esterification of cyclohexene with formic acid over a peanut shell-derived carbon solid acid catalyst [J]. Chinese Journal of Catalysis, 2016, 37(5): 769-777.
[8]	Yongle Chen, Shiya Ding, Wentao Zheng, Yiyang Zhang, Youting Wu, Xingbang Hu. Proton-gradient-transfer acid complexes and their catalytic performance for the synthesis of geranyl acetate [J]. Chinese Journal of Catalysis, 2016, 37(12): 2114-2121.
[9]	Tao Chang, Leqin He, Xiaojing Zhang, Mingxia Yuan, Shenjun Qin, Jiquan Zhao . Brönsted acid surfactant-combined dicationic ionic liquids as green catalysts for biodiesel synthesis from free fatty acids and alcohols [J]. Chinese Journal of Catalysis, 2015, 36(7): 982-986.
[10]	Huanwang Jing, Xiaomei Wang, Yong Liu, Anqi Wang. Preparation of magnetic nanocomposites of solid acid catalysts and their applicability in esterification [J]. Chinese Journal of Catalysis, 2015, 36(2): 244-251.
[11]	Wei Wang, Zhenxin Xu, Zhanglong Guo, Chengfa Jiang, Wei Chu. Layered double hydroxide and related catalysts for hydrogen production and a biorefinery [J]. Chinese Journal of Catalysis, 2015, 36(2): 139-147.
[12]	Liping Zheng, Shuixin Xia, Xiuyang Lu, Zhaoyin Hou. Transesterification of glycerol with dimethyl carbonate over calcined Ca-Al hydrocalumite [J]. Chinese Journal of Catalysis, 2015, 36(10): 1759-1765.
[13]	Attaullah Bukhari, Ani Idris, Madiha Atta, Teo Chee Loong. Covalent immobilization of Candida antarctica lipase B on nanopolystyrene and its application to microwave-assisted esterification [J]. Chinese Journal of Catalysis, 2014, 35(9): 1555-1564.
[14]	Fubao Zhang, Xiaopeng Yu, Fei Ma, Xiangui Yang, Jing Hu, Zhiyong Deng, Gongying Wang. Transesterification of dimethyl oxalate with phenol over a MoO₃/SiO₂ catalyst prepared by thermal spreading [J]. Chinese Journal of Catalysis, 2014, 35(7): 1043-1053.
[15]	Petr Kutálek, Libor Čapek, Lucie Smoláková, David Kubička, Martin Hájek. Aspects of stability of K/Al₂O₃ catalysts for the transesterification of rapeseed oil in batch and fixed-bed reactors [J]. Chinese Journal of Catalysis, 2014, 35(7): 1084-1090.

Microwave Synthesis of a&b-Oriented Zeolite T Membranes and Their Application in Pervaporation-Assisted Esterification

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics