Chinese Journal of Catalysis ›› 2008, Vol. 29 ›› Issue (5): 421-425.

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Preparation of Pt/Al2O3 Metallic Honeycomb Catalyst and Its Catalytic Properties for CO Preferential Oxidation

ZHANG Jianguo1,2, JIA Jingsheng1, ZHANG Chunxi1, WANG Shudong\{1*\}   

  1. 1 Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China; 2 Graduate University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2008-05-25 Online:2008-05-25 Published:2012-05-02

Abstract: A Pt/Al2O3 metallic honeycomb catalyst was prepared and studied in the CO preferential oxidation. The surface of the Fe-20Cr-5Al metallic substrate (400 cells/in2) appeared needle shape structure when it was oxided at 900 ℃ for 10 h. The optimal Al2O3 coating procedure was slurry-sol-slurry. The metallic honeycomb catalyst showed CO conversion of 54.0% and CO selectivity of 42.5% in CO preferential oxidation at 120 ℃, which were 1.7 and 1.4 times that of the ceramic honeycomb catalyst, respectively.

Key words: metallic honeycomb catalyst, high-temperature oxidation, carbon monoxide, preferential oxidation