Chinese Journal of Catalysis ›› 2007, Vol. 28 ›› Issue (12): 1112-1116.
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CHENG Wenping, WANG Wenjuan, LIU Ling, ZHAO Yuechang, YANG Jianguo*, HE Mingyuan
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Abstract: A series of MgAlCuFe complex oxides used for the removal of SOx from FCC flue gas were prepared by decomposition of MgAlCuFe hydrotalcite precursors at 700 ℃ for 6 h. The influence of different metal salts in the sulfur transfer catalyst was investigated.X-raydiffraction, thermogravimetric analysis, N2 adsorption, and infrared spectroscopy showed that all the sulfur transfer catalysts exhibited a better dispersion of metal oxides in the matrix. The results of the SO2 adsorption-reduction test showed that the novel catalyst MgAlCuFe prepared from nitrates reached 1.54 g/g of total saturation adsorption capacity in6 minunder the conditions similar to those of typical FCC. These catalysts achieved high oxidative adsorption rate, short saturation time, and large reductive capacity.
Key words: sulfur transfer catalyst, hydrotalcite-like compound, complex oxide, metal salt, sulfur oxidative adsorption, reductive desorption
CHENG Wenping;WANG Wenjuan;LIU Ling;ZHAO Yuechang;YANG Jianguo*;HE Mingyuan. Properties of MgAlCuFe Complex Oxides for FCC Desulfurization: Effect of Metal Salt Precursors[J]. Chinese Journal of Catalysis, 2007, 28(12): 1112-1116.
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