Chinese Journal of Catalysis ›› 2007, Vol. 28 ›› Issue (7): 646-650.

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Comparison of Electrocatalytic Performance of Different Anodes with Cyclic Voltammetry and Tafel Curves

DING Haiyang, FENG Yujie*, LIU Junfeng   

  1. Department of Environmental Science and Engineering, Harbin Institute of Technology, Harbin 150090, Heilongjiang, China
  • Received:2007-07-25 Online:2007-07-25 Published:2011-07-25

Abstract: The eletrocatalytic capability of Pt, Ti base RuO2 (Ti/RuO2), and Ti base SnO2 (Ti/SnO2) electrodes was evaluated with cyclic voltammetry (CV) and Tafel curves. CV curves of the three electrodes were measured in 500 mg/L phenol solution, and their phenol oxidation peak potentials were around 0.93, 0.95, and 1.40 V (vs Ag/AgCl), respectively. The capability of direct electrocatalytic oxidation of phenol lied in the sequence of Pt<Ti/SnO2<Ti/RuO2. The Tafel curves were measured in 0.1 mol/L H2SO4 and the results showed that the oxygen evolution overpotentials of the three electrodes increased in the order Ti/RuO2

Key words: electrocatalysis, anode, cyclic voltammetry, Tafel curve, hydroxyl radical, phenol, degradation