Efficient Synthesis of3,4-Dihydropyrimidin-2(1H)-one Using Metal Hydrogen Sulfates M(HSO4)n as Catalyst under Solvent-Free Conditions

Chinese Journal of Catalysis ›› 2007, Vol. 28 ›› Issue (7): 591-595.

• Articles • Previous Articles Next Articles

Efficient Synthesis of3,4-Dihydropyrimidin-2(1H)-one Using Metal Hydrogen Sulfates M(HSO4)n as Catalyst under Solvent-Free Conditions

Khodabakhsh NIKNAM1, Mohammad Ali ZOLFIGOL2, Zahra HOSSIENINEJAD2, Nader DANESHVAR2

1 Chemistry Department, Faculty of Sciences, Persian Gulf University, Bushehr 75169, Iran; 2 College of Chemistry, Bu-Ali Sina University, Hamadan 65174, Iran

Received:2007-07-25 Online:2007-07-25 Published:2011-07-25

Abstract

Abstract: Metal hydrogen sulfates M(HSO4)n(Ca(HSO4)2, Zn(HSO4)2, and oxone) were used to catalyze one-pot three-component condensation reactions of aldehydes,1,3-dicarbonyl compounds, and urea at 90 ℃ under solvent-free conditions to give3,4-dihydropyrimidin-2(1H)-one in high yields.

Key words: metal hydrogen sulfate, Biginelli reaction, dihydropyrimidinone, solvent-free, calcium hydrogen sulfate, zinc hydrogen sulfate, oxone

Khodabakhsh NIKNAM;Mohammad Ali ZOLFIGOL;Zahra HOSSIENINEJAD;Nader DANESHVAR. Efficient Synthesis of3,4-Dihydropyrimidin-2(1H)-one Using Metal Hydrogen Sulfates M(HSO4)n as Catalyst under Solvent-Free Conditions[J]. Chinese Journal of Catalysis, 2007, 28(7): 591-595.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/

https://www.cjcatal.com/EN/Y2007/V28/I7/591

[1]	Zhiyue Zhao, Zhiwei Jiang, Yizhe Huang, Mebrouka Boubeche, Valentina G. Matveeva, Hector F. Garces, Huixia Luo, Kai Yan. Facile synthesis of CoSi alloy catalysts with rich vacancies for base- and solvent-free aerobic oxidation of aromatic alcohols [J]. Chinese Journal of Catalysis, 2023, 48(5): 175-184.
[2]	Dan Zhang, Hongfu Miao, Xueke Wu, Zuochao Wang, Huan Zhao, Yue Shi, Xilei Chen, Zhenyu Xiao, Jianping Lai, Lei Wang. Scalable synthesis of ultra-small Ru₂P@Ru/CNT for efficient seawater splitting [J]. Chinese Journal of Catalysis, 2022, 43(4): 1148-1155.
[3]	Qiuyan Zhu, Yeqing Wang, Lingxiang Wang, Zhiyuan Yang, Liang Wang, Xiangju Meng, Feng-Shou Xiao. Solvent-free crystallization of ZSM-5 zeolite on SiC foam as a monolith catalyst for biofuel upgrading [J]. Chinese Journal of Catalysis, 2020, 41(7): 1118-1124.
[4]	Mudassar Javed, Shilin Cheng, Guihua Zhang, Cederick Cyril Amoo, Jingyan Wang, Peng Lu, Chengxue Lu, Chuang Xing, Jian Sun, Noritatsu Tsubaki. A facile solvent-free synthesis strategy for Co-imbedded zeolite-based Fischer-Tropsch catalysts for direct gasoline production [J]. Chinese Journal of Catalysis, 2020, 41(4): 604-612.
[5]	XIAO Feng-Shou. Green Synthesis: Novel Routes for Preparation of Zeolite Catalysts [J]. Chinese Journal of Catalysis, 2019, 40(s1): 26-29.
[6]	Jianwei Che, Mengjia Hao, Wuzhong Yi, Hisayoshi Kobayashi, Yuheng Zhou, Liping Xiao, Jie Fan. Selective suppression of toluene formation in solvent-free benzyl alcohol oxidation using supported Pd-Ni bimetallic nanoparticles [J]. Chinese Journal of Catalysis, 2017, 38(11): 1870-1879.
[7]	Mingzhou Wu, Wangcheng Zhan, Yun Guo, Yunsong Wang, Yanglong Guo, Xueqing Gong, Li Wang, Guanzhong Lu. Solvent-free selective oxidation of cyclohexane with molecular oxygen over manganese oxides: Effect of the calcination temperature [J]. Chinese Journal of Catalysis, 2016, 37(1): 184-192.
[8]	Abdol R. Hajipour, Hirbod Karimi, Afshin Koohi. Selective oxidation of alcohols over nickel zirconium phosphate [J]. Chinese Journal of Catalysis, 2015, 36(7): 1109-1116.
[9]	Xian Chen, Xiangju Meng, Feng-shou Xiao. Solvent-free synthesis of SAPO-5 zeolite with plate-like morphology in the presence of surfactants [J]. Chinese Journal of Catalysis, 2015, 36(6): 797-800.
[10]	Hossein Naeimi, Hossein Foroughi. Efficient, environmentally benign, one-pot procedure for the synthesis of 1, 5-benzodiazepine derivatives using N-methyl-2-pyrrolidonium hydrogen sulphate as an ionic liquid catalyst under solvent-free conditions [J]. Chinese Journal of Catalysis, 2015, 36(5): 734-741.
[11]	Abdol R. Hajipour, Hirbod Karimi, Amir Masti. Acetylation of alcohols and phenols under solvent-free conditions using iron zirconium phosphate [J]. Chinese Journal of Catalysis, 2015, 36(4): 595-602.
[12]	Hossein Eshghi, Ali Javid, Amir Khojastehnezhad, Farid Moeinpour, Fatemeh F. Bamoharram d, Mehdi Bakavoli, Masoud Mirzaei. Preyssler heteropolyacid supported on silica coated NiFe₂O₄ nanoparticles for the catalytic synthesis of bis(dihydropyrimidinone)benzene and 3,4-dihydropyrimidin-2(1H)-ones [J]. Chinese Journal of Catalysis, 2015, 36(3): 299-307.
[13]	Nader Ghaffari Khaligh. One-pot multicomponent synthesis of unsymmetrical polyhydroquinoline derivatives with 1,1’-butylenebispyridinium hydrogen sulfate as an efficient, halogen-free and reusable Brönsted ionic liquid catalyst [J]. Chinese Journal of Catalysis, 2014, 35(9): 1497-1503.
[14]	Bahador Karami, Mahtab Kiani, Mohsen Ahmad Hoseini. In(OTf)₃ as a powerful and recyclable catalyst for Pechmann condensation without solvent [J]. Chinese Journal of Catalysis, 2014, 35(7): 1206-1211.
[15]	Nader Ghaffari Khaligh, Parisa Ghods Ghasem-Abadi. N-Sulfonic acid poly(4-vinylpyridinum) hydrogen sulfate as a novel, efficient, and reusable solid acid catalyst for acylation under solvent-free conditions [J]. Chinese Journal of Catalysis, 2014, 35(7): 1126-1135.

Efficient Synthesis of3,4-Dihydropyrimidin-2(1H)-one Using Metal Hydrogen Sulfates M(HSO4)n as Catalyst under Solvent-Free Conditions

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics