Organotitanium Compound Catalysts for Transesterification of Dimethyl Carbonate and Phenyl Acetate to Diphenyl Carbonate

Chinese Journal of Catalysis ›› 2009, Vol. 30 ›› Issue (1): 65-68.

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Organotitanium Compound Catalysts for Transesterification of Dimethyl Carbonate and Phenyl Acetate to Diphenyl Carbonate

CAO Ping1,2,3, YANG Jian4, YANG Xiangui1,2, YAO Jie1,2, WANG Yue1,2, WANG Gongying1,2*

1 Chengdu Institute of Organic Chemistry, The Chinese Academy of Sciences, Chengdu 610041, Sichuan, China; 2 Changzhou Key Laboratory of Green Chemistry and Technology, Changzhou Institute of Chemistry, Changzhou 213164, Jiangsu, China; 3 Graduate University of Chinese Academy of Sciences, Beijing 100049, China; 4 Yabang Chemical Group Co., Ltd, Changzhou 213163, Jiangsu, China

Received:2009-01-25 Online:2009-01-25 Published:2012-10-17

Abstract

Abstract: An alternative method was studied for diphenyl carbonate (DPC) synthesis from di methyl car bonate (DMC) and phenyl acetate (PA) using a β-diketonate titanium complex, ti tan ium oxide acetylacetonate (TiO(acac)2), as the catalyst. TiO(acac)2 is an ef ficient catalyst for the transesterification reaction with a catalyst amount of 0.006 (mole ratio to PA).

Key words: titanium oxide acetylacetonate, dimethyl carbonate, phenyl acetate, transesterification, diphenyl carbonate

CAO Ping;;YANG Jian;YANG Xiangui;YAO Jie;WANG Yue;WANG Gongying;*. Organotitanium Compound Catalysts for Transesterification of Dimethyl Carbonate and Phenyl Acetate to Diphenyl Carbonate[J]. Chinese Journal of Catalysis, 2009, 30(1): 65-68.

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Organotitanium Compound Catalysts for Transesterification of Dimethyl Carbonate and Phenyl Acetate to Diphenyl Carbonate

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