Solvent-Free Oxidation of Alcohols Catalyzed by a Mn(III) Schiff-Base Complex Using Hydrogen Peroxide as an Oxidant

Abstract

Abstract: Aliphatic and aromatic alcohols are efficiently oxidized to ketones or carboxylic acids using aqueous hydrogen peroxide as an oxidant in the presence of a Mn(III) Schiff-base complex as a catalyst under solvent-free conditions. The oxidation of alcohols occurred at 50 °C to give the corresponding ketones or carboxylic acids with a yield higher than 60%.

Key words: alcohol, oxidation, hydrogen peroxide, Schiff-base complex, Mn(III) complex, ketone

Hamid GOLCHOUBIAN;*;Seyyed Ebrahim BABAEI. Solvent-Free Oxidation of Alcohols Catalyzed by a Mn(III) Schiff-Base Complex Using Hydrogen Peroxide as an Oxidant[J]. Chinese Journal of Catalysis, 2010, 31(6): 615-618.

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https://www.cjcatal.com/EN/Y2010/V31/I6/615

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Solvent-Free Oxidation of Alcohols Catalyzed by a Mn(III) Schiff-Base Complex Using Hydrogen Peroxide as an Oxidant

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