Hydrogenation of Quinoline Catalyzed by Ruthenium Phosphine Complex in Ionic Liquids

Chinese Journal of Catalysis ›› 2009, Vol. 30 ›› Issue (3): 242-246.

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Hydrogenation of Quinoline Catalyzed by Ruthenium Phosphine Complex in Ionic Liquids

LI Qiang1, ZHANG Ruimin1, ZHOU Limei1,2, FU Haiyan1, CHEN Hua1,*, LI Xianjun1

1Institute of Homogeneous Catalysis, College of Chemistry, Key Laboratory of Green Chemistry and Technology of Ministry of Education, Sichuan University, Chengdu 610064, Sichuan, China; 2Department of Chemistry and Chemical Engineering, West China Normal University, Nanchong 637002, Sichuan, China

Received:2009-03-25 Online:2009-03-25 Published:2012-12-19

Abstract

Abstract: The catalyst [RuCl2(TPPTS)2]2 was used in the regioselective hydrogenation of quinoline in [Rmim][p-CH3C6H4SO3] with high conversion and selectivity. The products can be easily separated from the catalyst immobilized in ionic liquids by simple extraction with cycohexane. The conversion reached 86.0% when the catalyst was reused 6 times.

Key words: ruthenium phosphine complex, quinoline, hydrogenation, ionic liquid, biphasic catalysis, 1, 2, 3, 4-tetrahydroquinoline

LI Qiang;ZHANG Ruimin;ZHOU Limei;FU Haiyan;CHEN Hua;*;LI Xianjun. Hydrogenation of Quinoline Catalyzed by Ruthenium Phosphine Complex in Ionic Liquids[J]. Chinese Journal of Catalysis, 2009, 30(3): 242-246.

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Hydrogenation of Quinoline Catalyzed by Ruthenium Phosphine Complex in Ionic Liquids

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