Synthesis of Carbon Nanotubes-Supported Pd/SnO2 for the Hydrogenation of ortho-Chloronitrobenzene

Abstract

Abstract: A new method was developed for the synthesis of Pd/SnO2/CNTs nano-catalysts, in which three steps are involved: the adsorption of Sn2+ on the surface of CNTs, the addition and reduction of Pd2+ by Sn2+, and the formation of SnO2 due to the hydrolyzation of Sn4+. The as-obtained Pd/SnO2/CNTs catalysts show high ortho-chloroaniline selectivity in the hydrogenation of chloronitrobenzene.

Key words: carbon nanotube, palladium, tin dioxide, chloronitrobenzene, selective hydrogenation, chloroaniline

WANG Chuang;QIU Jieshan*;LIANG Changhai. Synthesis of Carbon Nanotubes-Supported Pd/SnO2 for the Hydrogenation of ortho-Chloronitrobenzene[J]. Chinese Journal of Catalysis, 2009, 30(3): 259-264.

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https://www.cjcatal.com/EN/Y2009/V30/I3/259

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Synthesis of Carbon Nanotubes-Supported Pd/SnO2 for the Hydrogenation of ortho-Chloronitrobenzene

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