Molybdenum Trioxide Catalyst for Transesterification of Dimethyl Carbonate and Phenyl Acetate to Diphenyl Carbonate

Chinese Journal of Catalysis ›› 2009, Vol. 30 ›› Issue (9): 853-855.

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Molybdenum Trioxide Catalyst for Transesterification of Dimethyl Carbonate and Phenyl Acetate to Diphenyl Carbonate

CAO Ping1,2,3, YANG Xiangui1,3, TANG Congming1,2,3, YANG Jian4, YAO Jie1,3, WANG Yue1,3, WANG Gongying1,3,*

1Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, Sichuan, China 2Graduate University of Chinese Academy of Sciences, Beijing 100049, China 3Changzhou Key Laboratory of Green Chemistry & Technology, Changzhou Institute of Chem-istry, Changzhou 213164, Jiangsu, China 4Yabang Chemical Group Co., Ltd., Changzhou 213163, Jiangsu, China

Received:2009-09-25 Online:2009-09-25 Published:2009-09-25

Abstract

Abstract: A MoO3 catalyst for the transesterification of phenyl acetate and dimethyl carbonate to diphenyl carbonate was prepared by calcination. The MoO3 calcined at 400 or 500 oC was an excellent catalyst, and it can be reused many times and regenerated simply by calcination while maintaining catalytic activity almost as high as the fresh sample.

Key words: molybdenum trioxide, transesterification, dimethyl carbonate, phenyl acetate, diphenyl carbonate

CAO Ping;;YANG Xiangui;TANG Congming;;YANG Jian;YAO Jie;WANG Yue;WANG Gongying;*. Molybdenum Trioxide Catalyst for Transesterification of Dimethyl Carbonate and Phenyl Acetate to Diphenyl Carbonate[J]. Chinese Journal of Catalysis, 2009, 30(9): 853-855.

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Molybdenum Trioxide Catalyst for Transesterification of Dimethyl Carbonate and Phenyl Acetate to Diphenyl Carbonate

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