Catalytic Oxidative Removal of Dimethylsulfoxide by Hexadentate 8-Quinolinolato Manganese(III) Complexes

Chinese Journal of Catalysis ›› 2009, Vol. 30 ›› Issue (10): 981-985.

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Catalytic Oxidative Removal of Dimethylsulfoxide by Hexadentate 8-Quinolinolato Manganese(III) Complexes

XIE Fang, FU Zaihui*, ZHONG Sheng, YE Zhengpei, ZHOU Xiaoping, LIU Fenglan, LU Chunli, RONG Chunying, MAO Liqiu, YIN Dulin

Key Laboratory of Resource Fine-Processing and Advanced Materials of Hunan Province, Key Laboratory of Chemical Biology and Tradi-tional Chinese Medicine Research of Ministry of Education, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, Hunan, China

Received:2009-10-25 Online:2009-10-25 Published:2013-06-06

Abstract

Abstract: A series of hexadentate 8-quinolinolato manganese(III) complexes (Q₃Mn^III), with NH₄OAc and HOAc as additives, were highly efficient catalysts for the oxidation of dimethylsulfoxide (DMSO) with aqueous hydrogen peroxide in an environmentally friendly acetone-water medium. The halogen substituents on the ligand improved the catalytic efficiency of Q₃Mn^III complexes, which was likely due to their strong distortion effect on Q₃Mn^III as indicated by the B3LYP/6-311G+(d) calculation. Various parameters were investigated and a reaction mechanism was proposed.

Key words: dimethylsulfoxide, catalytic oxidation, hexadentate 8-quinolinolato manganese(III) complex, hydrogen peroxide

XIE Fang;FU Zaihui*;ZHONG Sheng;YE Zhengpei;ZHOU Xiaoping;LIU Fenglan;LU Chunli;RONG Chunying;MAO Liqiu;YIN Dulin. Catalytic Oxidative Removal of Dimethylsulfoxide by Hexadentate 8-Quinolinolato Manganese(III) Complexes[J]. Chinese Journal of Catalysis, 2009, 30(10): 981-985.

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Catalytic Oxidative Removal of Dimethylsulfoxide by Hexadentate 8-Quinolinolato Manganese(III) Complexes

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