Different Carriers-Supported Rh-Based Catalysts for Oxidative Bromination of Methane

Chinese Journal of Catalysis ›› 2010, Vol. 31 ›› Issue (2): 213-217.

• Articles • Previous Articles Next Articles

Different Carriers-Supported Rh-Based Catalysts for Oxidative Bromination of Methane

LIN Ronghe1,3, DING Yunjie1,2,*, GONG Leifeng1,3, LI Jingwei1,3, CHEN Weimiao1, YAN Li1, LÜ Yuan1

1Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaon-ing, China 2State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaon-ing, China 3Graduate University of Chinese Academy of Sciences, Beijing 100049, China

Received:2010-02-25 Online:2010-02-25 Published:2013-09-02

Abstract

Abstract: Oxidative bromination of methane over different carriers-supported Rh-based catalysts showed that inert supports such as SiC and SiO2 were in favor of the selectivity for bromomethanes, but deep oxidation occurred over metal oxide-supported ones. The superior performance of inert carrier-supported catalysts was ascribed to the medium redox ability, which suppressed CH3Br steam reforming.

Key words: methane, oxidative bromination, rhodium, support, supported catalyst

LIN Ronghe;DING Yunjie;*;GONG Leifeng;LI Jingwei;CHEN Weimiao;YAN Li;LÜYuan. Different Carriers-Supported Rh-Based Catalysts for Oxidative Bromination of Methane[J]. Chinese Journal of Catalysis, 2010, 31(2): 213-217.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/

https://www.cjcatal.com/EN/Y2010/V31/I2/213

[1]	Sikai Wang, Xiang-Ting Min, Botao Qiao, Ning Yan, Tao Zhang. Single-atom catalysts: In search of the holy grails in catalysis [J]. Chinese Journal of Catalysis, 2023, 52(9): 1-13.
[2]	Lu Cheng, Xuning Chen, P. Hu, Xiao-Ming Cao. Advantages and limitations of hydrogen peroxide for direct oxidation of methane to methanol at mono-copper active sites in Cu-exchanged zeolites [J]. Chinese Journal of Catalysis, 2023, 51(8): 135-144.
[3]	Hao Zhang, Yaqiong Su, Nikolay Kosinov, Emiel J. M. Hensen. Non-oxidative coupling of methane over Mo-doped CeO₂ catalysts: Understanding surface and gas-phase processes [J]. Chinese Journal of Catalysis, 2023, 49(6): 68-80.
[4]	Zheng-Qing Huang, Shu-Yue He, Tao Ban, Xin Gao, Yun-Hua Xu, Chun-Ran Chang. Mechanistic and microkinetic study of nonoxidative coupling of methane on Pt-Cu alloy catalysts: From single-atom sites to single-cluster sites [J]. Chinese Journal of Catalysis, 2023, 48(5): 90-100.
[5]	Fengwei Zhang, Hefang Guo, Mengmeng Liu, Yang Zhao, Feng Hong, Jingjing Li, Zhengping Dong, Botao Qiao. Enhancing the chemoselective hydrogenation of nitroarenes: Designing a novel surface-strained carbon-based Pt nanocatalyst [J]. Chinese Journal of Catalysis, 2023, 48(5): 195-204.
[6]	Keran Wang, Lei Luo, Chao Wang, Junwang Tang. Photocatalytic methane activation by dual reaction sites co-modified WO₃ [J]. Chinese Journal of Catalysis, 2023, 46(3): 103-112.
[7]	Hua Liu, Leilei Kang, Hua Wang, Qike Jiang, Xiao Yan Liu, Aiqin Wang. Ru single-atom catalyst anchored on sulfated zirconia for direct methane conversion to methanol [J]. Chinese Journal of Catalysis, 2023, 46(3): 64-71.
[8]	Yiming Lei, Jinhua Ye, Jordi García-Antón, Huimin Liu. Recent advances in the built-in electric-field-assisted photocatalytic dry reforming of methane [J]. Chinese Journal of Catalysis, 2023, 53(10): 72-101.
[9]	Huayang Zhang, Wenjie Tian, Xiaoguang Duan, Hongqi Sun, Yingping Huang, Yanfen Fang, Shaobin Wang. Single-atom catalysts on metal-based supports for solar photoreduction catalysis [J]. Chinese Journal of Catalysis, 2022, 43(9): 2301-2315.
[10]	Guang Gao, Zelun Zhao, Jia Wang, Yongjie Xi, Peng Sun, Fuwei Li. Boosting chiral carboxylic acid hydrogenation by tuning metal-MO_x-support interaction in Pt-ReO_x/TiO₂ catalysts [J]. Chinese Journal of Catalysis, 2022, 43(8): 2034-2044.
[11]	Ernest Pahuyo Delmo, Yian Wang, Jing Wang, Shangqian Zhu, Tiehuai Li, Xueping Qin, Yibo Tian, Qinglan Zhao, Juhee Jang, Yinuo Wang, Meng Gu, Lili Zhang, Minhua Shao. Metal organic framework-ionic liquid hybrid catalysts for the selective electrochemical reduction of CO₂ to CH₄ [J]. Chinese Journal of Catalysis, 2022, 43(7): 1687-1696.
[12]	Peng Li, Guoqiang Zhao, Ningyan Cheng, Lixue Xia, Xiaoning Li, Yaping Chen, Mengmeng Lao, Zhenxiang Cheng, Yan Zhao, Xun Xu, Yinzhu Jiang, Hongge Pan, Shi Xue Dou, Wenping Sun. Toward enhanced alkaline hydrogen electrocatalysis with transition metal-functionalized nitrogen-doped carbon supports [J]. Chinese Journal of Catalysis, 2022, 43(5): 1351-1359.
[13]	Chunpeng Wang, Zhe Wang, Shanjun Mao, Zhirong Chen, Yong Wang. Coordination environment of active sites and their effect on catalytic performance of heterogeneous catalysts [J]. Chinese Journal of Catalysis, 2022, 43(4): 928-955.
[14]	Peng Wu, Jinyan Zhang, Qianqian Chen, Wei Peng, Binju Wang. Theoretical perspective on mononuclear copper-oxygen mediated C-H and O-H activations: A comparison between biological and synthetic systems [J]. Chinese Journal of Catalysis, 2022, 43(4): 913-927.
[15]	Junhui Liu, Yakun Song, Xuming Guo, Chunshan Song, Xinwen Guo. Recent advances in application of iron-based catalysts for CO_x hydrogenation to value-added hydrocarbons [J]. Chinese Journal of Catalysis, 2022, 43(3): 731-754.

Different Carriers-Supported Rh-Based Catalysts for Oxidative Bromination of Methane

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics