Preparation of Immobilized Chromium Schiff Base Complexes and Their Catalytic Performance for Cyclohexene Epoxidation

doi:10.1016/S1872-2067(10)60272-0

Abstract

Abstract: Three typical amino acid Schiff base chromium(III) complexes immobilized on MCM-41 were prepared and characterized by various physico-chemical methods such as Fourier transform infrared spectroscopy, ultraviolet-visible spectroscopy, X-ray powder diffraction, N₂ sorption, and elemental analysis. The obtained immobilized complexes were effective catalysts for the epoxidation of cyclohexene with 30% hydrogen peroxide and they exhibited significantly enhanced catalytic performance compared with their corresponding homogeneous analogues. Under optimal reaction conditions the highest conversion of cyclohexene was 52.6% with 73.5% epoxide selectivity. In addition, the catalytic activity was retained after recycling 6 times.

Key words: immobilized, amino acid, Schiff base complex, cyclohexene, epoxidation

WANG Xiao-Li, WU Gong-De, WANG Fang, WEI Wei, SUN Yu-Han. Preparation of Immobilized Chromium Schiff Base Complexes and Their Catalytic Performance for Cyclohexene Epoxidation[J]. Chinese Journal of Catalysis, 2011, 32(12): 1812-1821.

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