Preparation of 2D Hexagonal p6mm Ordered Mesoporous WO3-TiO2 Composite Materials and Their Visible-Light Photocatalytic Activity

doi:10.3724/SP.J.1088.2011.10841

Abstract

Abstract: A series of ordered mesoporous WO₃-TiO₂ composite materials with different WO₃ loadings were prepared by using a single step nonionic-surfactant-templating combined with evaporation-induced self-assembly (EISA) technique. The mesostructure, morphology, porosity, optical property, and composition of as-prepared materials were characterized. The characterization results confirmed that the ordered composite materials exhibited 2D hexagonal p6mm symmetry and anatase phase structure with larger BET surface area (152–154 m²/g) and more uniform pore size (5.3 nm) compared with the disordered WO₃-TiO₂ composite material as well as narrow bandgap (3.0 eV) with respect to pure TiO₂. Subsequently, the ordered mesoporous composite materials were successfully applied to the degradation of rhodamine B and 2,4-dichlorophenoxy acetic acid in the liquid phase under visible-light (l > 400 nm) irradiation, and enhanced photocatalytic activity compared with the disordered WO₃-TiO₂ composite material and pure TiO₂ was obtained for the samples with suitable WO₃ loadings.

Key words: tungsten trioxide, titania, ordered mesoporous material, photocatalysis, rhodamine B, 2,4-dichlorophenoxy acetic acid

HUANG Yan, LI Ke-Xin, YAN Liu-Shui, DAI Yu-Hua, HUANG Zhi-Min, XUE Kun-Peng, GUO Hui-Qin, XIONG Jing-Jing. Preparation of 2D Hexagonal p6mm Ordered Mesoporous WO₃-TiO₂ Composite Materials and Their Visible-Light Photocatalytic Activity[J]. Chinese Journal of Catalysis, 2012, 33(2): 308-316.

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URL: https://www.cjcatal.com/EN/10.3724/SP.J.1088.2011.10841

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Preparation of 2D Hexagonal p6mm Ordered Mesoporous WO₃-TiO₂ Composite Materials and Their Visible-Light Photocatalytic Activity

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