Preparation and Photocatalytic Activity of Lanthanide Loaded Microporous Titanosilicate ETS-10 Catalysts

doi:10.1016/S1872-2067(10)60293-8

Abstract

Abstract: The three dimensional microporous titanosilicate, ETS-10, was synthesized by a hydrothermal synthesis route using TiCl₄ and a sodium silicate aqueous solution as starting materials. Lanthanide (La, Ce, Pr, Nd) loaded ETS-10 catalysts were prepared by the impregnation method. The catalysts were characterized by X-ray diffraction, ²⁹Si magic angle spinning NMR, UV-Vis diffuse reflectance spectroscopy, N₂ adsorption-desorption measurement, and X-Ray fluorescence spectroscopy. The degradation of methyl orange under near-UV light was used to investigate the photocatalytic activity of the catalysts in aqueous suspensions. The lanthanide loaded ETS-10 catalysts exhibit higher activity than the unmodified ETS-10. The combination of loading lanthanide and increasing the surface defects of ETS-10 by a HF treatment gave an enhancement of the photocatalytic activity, which became comparable with that of anatase TiO₂.

Key words: microporous titanosilicate, Engelhard titanosilicate material number 10 (ETS-10), lanthanide, photocatalysis, methyl orange

REN Yuan-Hang, GU Min, HU Yi-Chen, YUE Bin, JIANG Lei, KONG Zu-Ping, HE He-Yong-b. Preparation and Photocatalytic Activity of Lanthanide Loaded Microporous Titanosilicate ETS-10 Catalysts[J]. Chinese Journal of Catalysis, 2012, 33(1): 123-128.

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