Novel Approach to Benzimidazoles Using Fe3O4 Nanoparticles as a Magnetically Recoverable Catalyst

doi:10.1016/S1872-2067(11)60329-X

Chinese Journal of Catalysis ›› 2012, Vol. 33 ›› Issue (2): 298-301.DOI: 10.1016/S1872-2067(11)60329-X

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Novel Approach to Benzimidazoles Using Fe₃O₄ Nanoparticles as a Magnetically Recoverable Catalyst

Bahador KARAMI1,*, Shaghayegh NIKOSERESHT2, Saeed KHODABAKHSHI1

1Department of Chemistry, Yasouj University, Yasouj, Iran; 2Department of Chemistry, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran

Received:2011-08-24 Revised:2011-11-07 Online:2012-02-20 Published:2015-07-27

Abstract

Abstract: Magnetically recoverable Fe₃O₄ nanoparticles have been synthesized as a catalyst for the cyclocondensation of 1,2- phenylenediamines with orthoesters under solvent-free conditions. Catalyst loadings can be as low as 1 mol% to give high yields of the corresponding benzimidazole derivative at 80 °C. This green method offers significant advantages in terms of its simplicity, low catalyst loadings, high product yields, and non-toxic nature. The Fe₃O₄ nanoparticles were characterized by X-ray diffraction, transmission electron microscopy, and Fourier transform infrared spectroscopy.

Key words: ferroferric oxide nanoparticle, 1,2-phenylenediamine, orthoester, benzimidazole

Bahador KARAMI, Shaghayegh NIKOSERESHT, Saeed KHODABAKHSHI. Novel Approach to Benzimidazoles Using Fe₃O₄ Nanoparticles as a Magnetically Recoverable Catalyst[J]. Chinese Journal of Catalysis, 2012, 33(2): 298-301.

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Novel Approach to Benzimidazoles Using Fe₃O₄ Nanoparticles as a Magnetically Recoverable Catalyst

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