Nanocasting, Template Synthesis, and Structural Studies on Cesium Salt of Phosphotungstic Acid for the Synthesis of Novel 1,3,5-Triaryl-pyrazoline Derivatives

doi:10.1016/S1872-2067(11)60330-6

Abstract

Abstract: The elimination of the silica matrix of composites by HF occurred by a two-step reaction deposition of a Cs_2.5H_0.5PW₁₂O₄₀ (CsHPW) salt nanocrystal. We used 2D hexagonal SBA-15 silica as a template for the nanofabrication of CsHPW nanoparticles. Nanocast CsHPW materials are stable against leaching and colloidization in polar solvents. The catalytic performance of the nanocast CsHPW materials exceeded that of bulk Cs_2.5H_0.5PW₁₂O₄₀, which is the most active among the acidic HPW salts. A series of novel 1,3,5-triaryl-pyrazoline derivatives were synthesized by the reaction between chalcone and phenylhydrazine in high yield in the presence of CsHPW salt nanocrystals.

Key words: nanocasting, nanoparticle, green chemistry, 1,3,5-triaryl-2-pyrazoline, polyoxometalate

Razieh FAZAELI, Hamid ALIYAN, Shahram TANGESTANINEJAD, Esmaeel MOHAMMADI, Maryam BORDBAR. Nanocasting, Template Synthesis, and Structural Studies on Cesium Salt of Phosphotungstic Acid for the Synthesis of Novel 1,3,5-Triaryl-pyrazoline Derivatives[J]. Chinese Journal of Catalysis, 2012, 33(2): 237-246.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(11)60330-6

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