Rh Nanoparticles Catalyzed Hydroformylation of Olefins in a Thermoregulated Ionic Liquid/Organic Biphasic System

doi:10.1016/S1872-2067(11)60371-9

Abstract

Abstract: Rh nanoparticles were investigated as a catalyst for hydroformylation of olefins in thermoregulated ionic liquid/organic biphasic systems composed of an ionic liquid, namely [CH₃(OCH₂CH₂)₁₆N⁺Et₃][CH₃SO₃⁻] (IL_PEG750), and an organic solvent. This enables not only a homogeneous reaction but also easy biphasic separation. Under the optimized reaction conditions, the conversion of 1-octene and yield of aldehyde were 99% and 91%, respectively. The catalyst was easily separated from the product by phase separation and used eight times without evident loss of activity.

Key words: hydroformylation, rhodium, nanoparticle, olefin, thermoregulated ionic liquid/organic biphasic system

ZENG Yan, WANG Yan-Hua, XU Yi-Cheng, SONG Ying, ZHAO Jia-Qi, JIANG Jing-Yang, JIN Zi-Lin. Rh Nanoparticles Catalyzed Hydroformylation of Olefins in a Thermoregulated Ionic Liquid/Organic Biphasic System[J]. Chinese Journal of Catalysis, 2012, 33(3): 402-406.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(11)60371-9

https://www.cjcatal.com/EN/Y2012/V33/I3/402

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Rh Nanoparticles Catalyzed Hydroformylation of Olefins in a Thermoregulated Ionic Liquid/Organic Biphasic System

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