One-Pot Four-Component Dakin-West Synthesis of β-Acetamido Ketones Catalyzed by a Vanadium-Substituted Heteropolyacid

doi:10.1016/S1872-2067(11)60379-3

Abstract

Abstract: The multicomponent condensation of an aryl aldehyde, acetyl chloride, acetonitrile, and enolizable ketone as one-pot synthesis of β-acetamido ketones in high yields was investigated using commercial, non-corrosive, and environmentally benign Keggin and Wells-Dawson heteropolyacid catalysts. The best catalyst was H₅PW₁₀V₂O₄₀. The methodology used simple experimental conditions, and the short reaction times and high yields indicate it is a useful strategy for the large scale synthesis of β-acetamido ketones.

Key words: homogeneous catalysis, heteropolyacid, Keggin, Wells-Dawson, Dakin-West, β-acetamido ketone

Reza TAYEBEE, Shima TIZABI. One-Pot Four-Component Dakin-West Synthesis of β-Acetamido Ketones Catalyzed by a Vanadium-Substituted Heteropolyacid[J]. Chinese Journal of Catalysis, 2012, 33(6): 923-932.

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