Regioselective Rhodium-Diphosphine Ligand Catalyzed Hydroformylation of Vinyl Acetate

doi:10.1016/S1872-2067(11)60384-7

Abstract

Abstract: Rhodium-catalyzed hydroformylation of vinyl acetate with the use of diphosphine ligands was studied. A high regioselectivity (branched:linear of 99:1) and activity (TOF: 4000 h⁻¹) under optimum conditions were achieved by using a 2,2’-bis(diphenylphosphino methyl)-1,1’-biphenyl ligand. The high turnover number (9200) obtained under mild conditions and stability of the catalyst indicates that it would be useful for industrial vinyl acetate hydroformylation.

Key words: vinyl acetate, hydroformylation, regioselectivity, diphosphine ligand, 2-acetoxypropanal

LIANG Hao-Ran, ZHANG Lin, ZHENG Xue-Li, FU Hai-Yan, YUAN Mao-Lin, LI Rui-Xiang, CHEN Hua. Regioselective Rhodium-Diphosphine Ligand Catalyzed Hydroformylation of Vinyl Acetate[J]. Chinese Journal of Catalysis, 2012, 33(6): 977-981.

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