Effect of Activation Temperature on Catalytic Performance of CuBTC for CO Oxidation

doi:10.1016/S1872-2067(11)60389-6

Abstract

Abstract: CuBTC (BTC = benzene-1,3,5-tricarboxylate), an metal-organic framework (MOF), is active for CO oxidation. The activation temperature has a significant effect on its activity. In-situ diffuse reflectance Fourier transform infrared spectroscopy, powder X-ray diffraction, scanning electron microscopy, and thermogravimetric analysis and differential scanning calorimetry (TGA/DSC) characterization showed that the coordination of CO on the open metal sites occurred during the oxidation reaction, and more open metal sites in the CuBTC framework gave a higher activity.

Key words: metal-organic framework, copper benzene-1,3,5-tricarboxylate, carbon monoxide, activation condition, gas-solid catalysis

QIU Wen-Ge, WANG Yu, LI Chuan-Qiang, ZHAN Zong-Cheng, ZI Xue-Hong, ZHANG Gui-Zhen, WANG Rui, HE Hong. Effect of Activation Temperature on Catalytic Performance of CuBTC for CO Oxidation[J]. Chinese Journal of Catalysis, 2012, 33(6): 986-992.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(11)60389-6

https://www.cjcatal.com/EN/Y2012/V33/I6/986

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