Silica-Bonded N-Propyl Diethylenetriamine Sulfamic Acid as a Recyclable Solid Acid Catalyst for the Synthesis of α-Aminonitriles

doi:10.1016/S1872-2067(11)60383-5

Abstract

Abstract: Silica-bonded N-propyl diethylenetriamine sulfamic acid (SBPDSA) is employed as a recyclable catalyst to synthesize α-aminonitriles. These syntheses involved one-pot condensation of an aldehyde, an amine, and trimethylsilyl cyanide under mild reaction conditions at room temperature. SBPDSA was recycled seven times in the condensation of benzaldehyde, aniline, and trimethylsilyl cyanide without reduction of its catalytic activity.

Key words: silica-bonded N-propyl diethylenetriamine sulfamic acid, α-aminonitrile, solid acid, aldehyde, heterogeneous catalyst

Tahere RAHI, Mojtaba BAGHERNEJAD, Khodabakhsh NIKNAM. Silica-Bonded N-Propyl Diethylenetriamine Sulfamic Acid as a Recyclable Solid Acid Catalyst for the Synthesis of α-Aminonitriles[J]. Chinese Journal of Catalysis, 2012, 33(7): 1095-1100.

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