Mild and Highly Efficient Method for Synthesis of 14-Aryl(alkyl)- 14H-dibenzo[a,j]xanthenes and 1,8-Dioxooctahydroxanthene Derivatives Using Pentafluorophenyl Ammonium Triflate as a Novel Organocatalyst

doi:10.1016/S1872-2067(11)60393-8

Abstract

Abstract: A simple and facile synthesis of 14-aryl and alkyl-14H-dibenzo[a,j]xanthenes and 1,8-dioxooctahydroxanthene derivatives has been successfully developed by treatment of β-naphthol or dimedone with aldehydes under mild conditions in the presence of a pentafluorophenyl ammonium triflate (PFPAT) organocatalyst. These catalytic condensation reactions represent green chemical processes and the PFPAT organocatalyst is air-stable, cost-effective, easy to handle, and easily removed from the reaction mixtures.

Key words: pentafluorophenyl ammonium triflate, organocatalyst, xanthene, β-naphthol

Samad KHAKSAR, Nosratollah BEHZADI. Mild and Highly Efficient Method for Synthesis of 14-Aryl(alkyl)- 14H-dibenzo[a,j]xanthenes and 1,8-Dioxooctahydroxanthene Derivatives Using Pentafluorophenyl Ammonium Triflate as a Novel Organocatalyst[J]. Chinese Journal of Catalysis, 2012, 33(6): 982-985.

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