NiMo/γ-Al2O3 Catalysts from Ni Heteropolyoxomolybdate and Effect of Alumina Modification by B, Co, or Ni

doi:10.1016/S1872-2067(11)60376-8

Abstract

Abstract: A hydrotreating NiMo/γ-Al₂O₃ catalyst (12 wt% Mo and 1.1 wt% Ni) was prepared by impregnation of the support with the Anderson-type heteropolyoxomolybdate (NH₄)₄Ni(OH)₆Mo₆O₁₈. Before impregnation of the support, it was modified with an aqueous solution of H₃BO₃, Co(NO₃)₂, or Ni(NO₃)₂. The catalysts were investigated using N₂ adsorption, O₂ chemisorption, X-ray diffraction, UV-Vis spectroscopy, Fourier transform infrared spectroscopy, temperature-programmed reduction, temperature-programmed desorption, and X-ray photoelectron spectroscopy. The addition of Co, Ni, or B influenced the Al₂O₃ phase composition and gave increased catalytic activity for 1-benzothiophene hydrodesulfurization (HDS). X-ray photoelectron spectroscopy confirmed that the prior loading of Ni, Co or B increased the degree of sulfidation of the NiMo/γ-Al₂O₃ catalysts. The highest HDS activity was observed with the NiMo/γ-Al₂O₃ catalyst with prior loaded Ni.

Key words: nickel, cobalt, boron, nickel heteropolyoxomolybdate, hydrodesulfurization

Radostina PALCHEVA, Luděk KALU?A, Alla SPOJAKINA, Květu?e JIRáTOVá, Georgi TYULIEV. NiMo/γ-Al₂O₃ Catalysts from Ni Heteropolyoxomolybdate and Effect of Alumina Modification by B, Co, or Ni[J]. Chinese Journal of Catalysis, 2012, 33(6): 952-961.

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NiMo/γ-Al₂O₃ Catalysts from Ni Heteropolyoxomolybdate and Effect of Alumina Modification by B, Co, or Ni

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