Effect of Zirconium in La(Ba)ZrxCo1-xO3-δ Perovskite Catalysts for N2O Decomposition

doi:10.1016/S1872-2067(11)60402-6

Abstract

Abstract: Zr-incorporated La(Ba)Zr_xCo_1-xO_3-δ perovskites were prepared by a sol-gel method and used for the catalytic decomposition of the high concentrations of N₂O present in propulsion applications. The introduction of Zr significantly enhanced N₂O conversion, esp. with x = 0.05 and 0.2 for LaZr_xCo_1-xO_3-δand BaZr_xCo_1-xO_3-δ, respectively. N₂ adsorption, X-ray diffraction, temperature-programmed reduction of H₂, temperature-programmed desorption of O₂, and oxygen pulse chemisorption techniques were used to characterize the structure and redox and oxygen adsorption property of the perovskites. The increasing of the surface area, modifying of the crystal structure, more facile reducibility of cobalt species, and higher oxygen desorption-adsorption activity due to the introduction of Zr were the reasons for the activity enhancement for N₂O decomposition.

Key words: lanthanum cobaltate, barium cobaltate, zirconium, nitrous oxide, decomposition

LIU Shuang, CONG Yu, Charles KAPPENSTEIN, ZHANG Tao. Effect of Zirconium in La(Ba)Zr_xCo_1-xO_3-δ Perovskite Catalysts for N₂O Decomposition[J]. Chinese Journal of Catalysis, 2012, 33(6): 907-913.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(11)60402-6

https://www.cjcatal.com/EN/Y2012/V33/I6/907

References

1 Balcon S, Mary S, Kappenstein C, Gengembre E. Appl Catal A, 2000, 196: 179
2 Wallbank J R, Sermon P A, Baker A M, Courtney L, Sambrook R M. The 2nd International Conference on Green Propellants for Space Propulsion. Italy, 2004
3 Zakirov V, Sweeting M, Lawrence T, Sellers J. Acta Astronaut, 2001, 48: 353
4 Zhao X Y, Cong Y, Lü F, Li L, Wang X D, Zhang T. Chem Commun, 2010, 46: 3028
5 Zhu S M, Wang X D, Wang A Q, Cong Y, Zhang T. Chem Commun, 2007: 1695
6 Zhao X Y, Cong Y, Huang Y Q, Liu S, Wang X D, Zhang T. Catal Lett, 2011, 141: 128
7 Liu S, Cong Y, Huang Y Q, Zhao X Y, Zhang T. Catal Today, 2011, 175: 264
8 Zhu S M, Wang X D, Wang A Q, Zhang T. Catal Today, 2008, 131: 339
9 Tian M, Wang A, Wang X, Zhu Y, Zhang T. Appl Catal B, 2009, 92: 437
10 Perez-Ramirez J, Santiago M. Chem Commun, 2007: 619
11 Alifanti M, Kirchnerova J, Delmon B, Klvana D. Appl Catal A, 2004, 262: 167
12 Buchneva O, Rossetti I, Biffi C, Allieta M, Kryukov A, Lebedeva N. Appl Catal A, 2009, 370: 24
13 Pena M A, Fierro J L G. Chem Rev, 2001, 101: 1981
14 Ishihara T, Kilner J A, Honda M, Sakai N, Yokokawa H, Takita Y. Solid State Ionics, 1998, 113–115: 593
15 Kapteijn F, Rodriguez-Mirasol J, Moulijn J A. Appl Catal B, 1996, 9: 25
16 Russo N, Mescia D, Fino D, Saracco G, Specchia V. Ind Eng Chem Res, 2007, 46: 4226
17 Hueso J L, Holgado J P, Pereniguez R, Mun S, Salmeron M, Caballero A. J Solid State Chem, 2010, 183: 27
18 Gunasekaran N, Rajadurai S, Carberry J J. Catal Lett, 1995, 35: 373
19 代小平, 余长春, 吴琼. 催化学报 (Dai X P, Yu Ch Ch, Wu Q. Chin J Catal), 2008, 29: 954
20 Dacquin J P, Dujardin C, Granger P. J Catal, 2008, 253: 37
21 Dacquin J P, Dujardin C, Granger P. Catal Today, 2008, 137: 390
22 Yao W, Wang R, Yang X. Catal Lett, 2009, 130: 613
23 Zhang R, Villanueva A, Alamdari H, Kaliaguine S. J Mol Catal A, 2006, 258: 22
24 Wang H, Zhao Z, Liang P, Xu C, Duan A, Jiang G, Xu J, Liu J. Catal Lett, 2008, 124: 91
25 Dai H, He H, Li P, Gao L, Au C T. Catal Today, 2004, 90: 231
26 马飞, 储伟, 黄利宏, 余晓鹏, 吴永永. 催化学报 (Ma F, Chu W, Huang L, Yu X, Wu Y. Chin J Catal), 2011, 32: 970
27 Shao Z P, Yang W S, Cong Y, Dong H, Tong J H, Xiong G X. J Membr Sci, 2000, 172: 177
28 Yang W S, Wang H H, Zhu X F, Lin L W. Top Catal, 2005, 35: 155
29 Doggali P, Kusaba S, Teraoka Y, Chankapure P, Rayalu S, Labhsetwar N. Catal Commun, 2010, 11: 665
30 Levasseur B, Kaliaguine S. Appl Catal B, 2009, 88: 305
31 Holmgren A, Andersson B, Duprez D. Appl Catal B, 1999, 22: 215
32 Zhu J, Thomas A. Appl Catal B, 2009, 92: 225
33 Dacquin J P, Lancelot C, Dujardin C, Da Costa P, Djega- Mariadassou G, Beaunier P, Kaliaguine S, Vaudreuil S, Royer S, Granger P. Appl Catal B, 2009, 91: 596
34 Navarro R M, Alvarez-Galvan M C, Villoria J A, González-Jiménez I D, Rosa F, Fierro J L G. Appl Catal B, 2007, 73: 247
35 Russo N, Furfori S, Fino D, Saracco G, Specchia V. Appl Catal B, 2008, 83: 85
36 Yao H C, Yao Y F Y. J Catal, 1984, 86: 254
37 Royer S, Alamdari H, Duprez D, Kaliaguine S. Appl Catal B, 2005, 58: 273

[1]	Keshia Saradima Indriadi, Peijie Han, Shipeng Ding, Bingqing Yao, Shinya Furukawa, Qian He, Ning Yan. Highly dispersed Pt boosts active Fe_xN formation in ammonia decomposition [J]. Chinese Journal of Catalysis, 2023, 50(7): 297-305.
[2]	Yujie Li, Yuanyuan Liu, Zeyan Wang, Peng Wang, Zhaoke Zheng, Hefeng Cheng, Ying Dai, Baibiao Huang. Enhanced photocatalytic H2O2 production over Pt(II) deposited boron containing metal-organic framework via suppressing the simultaneous decomposition [J]. Chinese Journal of Catalysis, 2023, 45(2): 132-140.
[3]	Bo Han, Jiong Zhang, Haijun Jiao, Lipeng Wu. Zirconium-hydride-catalyzed site-selective hydroboration of amides for the synthesis of amines: Mechanism, scope, and application [J]. Chinese Journal of Catalysis, 2021, 42(11): 2059-2067.
[4]	Yuanyuan Jiang, Ruru Zhou, Huaiyuan Zhao, Boyong Ye, Yihua Long, Zhengbao Wang, Zhaoyin Hou. A highly active and stable organic-inorganic combined solid acid for the transesterification of glycerol under mild conditions [J]. Chinese Journal of Catalysis, 2021, 42(10): 1772-1781.
[5]	Jinhua Zhang, Yuanbin She. Unveiling the decomposition mechanism of formic acid on Pd/WC(0001) surface by using density function theory [J]. Chinese Journal of Catalysis, 2020, 41(3): 415-425.
[6]	WANG Di, QIAO Yu, DENG Han, MU Xiaowei, HE Ping, ZHOU Haoshen. Research Progress and Characterization of Lithium-air Batteries [J]. Chinese Journal of Catalysis, 2019, 40(s1): 217-226.
[7]	Yan Zhang, Yuan Lyu, Yuqing Wang, Cunyao Li, Miao Jiang, Yunjie Ding. Highly active and stable porous polymer heterogenous catalysts for decomposition of formic acid to produce H₂ [J]. Chinese Journal of Catalysis, 2019, 40(2): 147-151.
[8]	Juan Zhang, Yueying Chu, Xiaolong Liu, Hao Xu, Xiangju Meng, Zhaochi Feng, Feng-Shou Xiao. Interzeolite transformation from FAU to CHA and MFI zeolites monitored by UV Raman spectroscopy [J]. Chinese Journal of Catalysis, 2019, 40(12): 1854-1859.
[9]	Jixing Liu, Zhen Zhao, Chunming Xu, Jian Liu. Structure, synthesis, and catalytic properties of nanosize cerium-zirconium-based solid solutions in environmental catalysis [J]. Chinese Journal of Catalysis, 2019, 40(10): 1438-1487.
[10]	Shuang Liu, Nanfang Tang, Qinghao Shang, Chuntian Wu, Guoliang Xu, Yu Cong. Superior performance of iridium supported on rutile titania for the catalytic decomposition of N₂O propellants [J]. Chinese Journal of Catalysis, 2018, 39(7): 1189-1193.
[11]	Dingkai Chen, Dehua Zhang, Dedong He, Jichang Lu, Liping Zhong, Caiyun Han, Yongming Luo. Relationship between oxygen species and activity/stability in heteroatom (Zr, Y)-doped cerium-based catalysts for catalytic decomposition of CH₃SH [J]. Chinese Journal of Catalysis, 2018, 39(12): 1929-1941.
[12]	Saeed Farhadi, Firouzeh Siadatnasab. CoFe₂O₄/CdS nanocomposite: Preparation, characterisation, and application in sonocatalytic degradation of organic dye pollutants [J]. Chinese Journal of Catalysis, 2016, 37(9): 1487-1495.
[13]	Baoqiang Xu, Haidi Xu, Tao Lin, Yi Cao, Li Lan, Yuanshan Li, Xi Feng, Maochu Gong, Yaoqiang Chen. Promotional effects of Zr on K⁺-poisoning resistance of CeTiO_x catalyst for selective catalytic reductionof NO_x with NH₃ [J]. Chinese Journal of Catalysis, 2016, 37(8): 1354-1361.
[14]	Minfang Wu, Hui Wang, Liangshu Zhong, Xinyan Zhang, Zhengping Hao, Qun Shen, Wei Wei, Guangren Qian, Yuhan Sun. Effects of acid pretreatment on Fe-ZSM-5 and Fe-beta catalysts for N₂O decomposition [J]. Chinese Journal of Catalysis, 2016, 37(6): 898-907.
[15]	Yuanyuan Lu, Guo Liu, Jing Zhang, Zhaochi Feng, Can Li, Zhi Li. Fabrication of a monoclinic/hexagonal junction in WO₃ and its enhanced photocatalytic degradation of rhodamine B [J]. Chinese Journal of Catalysis, 2016, 37(3): 349-358.

Effect of Zirconium in La(Ba)Zr_xCo_1-xO_3-δ Perovskite Catalysts for N₂O Decomposition

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics