Suzuki-Miyaura cross-coupling reaction catalyzed by a highly stable Pd(P-Phos)Cl2 complex at room temperature under air

doi:10.1016/S1872-2067(12)60620-2

Abstract

Abstract:

A new Pd(P-Phos)Cl₂ complex was synthesized and characterized by ¹H NMR, ¹³C NMR, ³¹P NMR, and X-ray single crystal structure determination. The complex proved to be a highly stable and efficient catalyst for substrates with a wide range of functional groups in Suzuki-Miyaura cross-coupling reactions under air at room temperature. Low catalyst loadings were employed and turnover number of up to 49000 was obtained.

Key words: Palladium complex, P-Phos, Suzuki-Miyaura cross-coupling reaction, Room temperature, Air

Yicen Ge, Yujing Cheng, Haiyan Fu, Xueli Zheng, Ruixiang Li, Hua Chen, Xianjun Li. Suzuki-Miyaura cross-coupling reaction catalyzed by a highly stable Pd(P-Phos)Cl₂ complex at room temperature under air[J]. Chinese Journal of Catalysis, 2013, 34(9): 1667-1673.

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Suzuki-Miyaura cross-coupling reaction catalyzed by a highly stable Pd(P-Phos)Cl₂ complex at room temperature under air

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