CoFe2O4 nanoparticles：An efficient heterogeneous magnetically separable catalyst for “click” synthesis of arylidene barbituric acid derivatives at room temperature

doi:10.1016/S1872-2067(12)60646-9

Abstract

Abstract:

A coprecipitation method was used to synthesize superparamagnetic CoFe₂O₄ nanoparticles without using any capping agents/surfactants. The prepared nanoparticles were characterized using Fourier transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, X-ray diffraction, a vibrating sample magnetometer (VSM), N₂ adsorption and thermogravimetric/differential thermal analysis/differential thermal gravimetry techniques. The synthesized spinel CoFe₂O₄ nanoparticles had an average size of 2-8 nm with a high surface area (140.9 m²/g). The field-dependent magnetization, demonstrated by VSM and saturation magnetization, was found to be 1.77 emu/g. An efficient method was used for the synthesis of arylidene barbituric acid derivatives using CoFe₂O₄ magnetic nanoparticles as a magnetically separable and reusable catalyst in aqueous ethanol. The attractive features of this synthetic protocol were very short reaction time, high yields, high turnover frequency, simple work-up procedure, economy, a clean reaction methodology, and chemoselectivity, as well as provision of an ecofriendly and green synthesis.

Key words: Magnetically separable catalyst, Arylidene barbituric acid derivative, Aqueous ethanol, Superparamagnetic CoFe₂O₄, nanoparticle, Heterogeneous catalyst

Jaspreet Kaur Rajput, Gagandeep Kaur. CoFe₂O₄ nanoparticles：An efficient heterogeneous magnetically separable catalyst for “click” synthesis of arylidene barbituric acid derivatives at room temperature[J]. Chinese Journal of Catalysis, 2013, 34(9): 1697-1704.

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CoFe₂O₄ nanoparticles：An efficient heterogeneous magnetically separable catalyst for “click” synthesis of arylidene barbituric acid derivatives at room temperature

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