Selective oxidation of alcohols over copper zirconium phosphate

doi:10.1016/S1872-2067(14)60096-6

Abstract

Abstract:

The catalytic activity of copper zirconium phosphate (ZPCu) in the selective oxidation of alcohols to their corresponding ketones or aldehydes, using H₂O₂ as an oxidizing agent, was studied. The oxidation reaction was performed without any organic solvent, phase-transfer catalyst, or additive. Steric factors associated with the substrates influenced the reaction. The catalyst was characterized using X-ray diffraction, inductively coupled plasma atomic emission spectroscopy, energy-dispersive X-ray spectroscopy, and scanning electron microscopy. It was shown that the interlayer distance increased from 0.74 to 0.80 nm and the crystallinity was reduced after Cu²⁺ intercalation into the layers. This catalyst can be recovered and reused three times without significant loss of activity and selectivity.

Key words: Copper zirconium phosphate, Selective oxidation, Solid catalyst, Alcohol

Abdol R. Hajipour, Hirbod Karimi. Selective oxidation of alcohols over copper zirconium phosphate[J]. Chinese Journal of Catalysis, 2014, 35(9): 1529-1533.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(14)60096-6

https://www.cjcatal.com/EN/Y2014/V35/I9/1529

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