Efficient synthesis of 1,8-dioxo-octahydroxanthenes catalyzed by β-cyclodextrin grafted with butyl sulfonic acid in aqueous media

doi:10.1016/S1872-2067(15)60888-9

Abstract

Abstract:

β-Cyclodextrin was functionalized with butyl sulfonic acid to give an efficient, eco-friendly catalyst for the synthesis of 1,8-dioxo-octahydroxanthenes via the one-pot condensation of aromatic aldehydes and active methylene carbonyl compounds in aqueous media. This new methodology offers several advantages such as excellent yields, short reaction time, a simple procedure and mild reaction conditions. Furthermore, the catalyst can be readily recovered and reused up to five times without a significant loss in its activity.

Key words: One-pot synthesis, Acidic catalyst, β-Cyclodextrin bearing butyl sulfonic acid, 1,8-Dioxo-octahydroxanthenes, Aqueous media

Kai Gong, Hualan Wang, Shuxin Wang, Ying Wang, Jinghua Chen. Efficient synthesis of 1,8-dioxo-octahydroxanthenes catalyzed by β-cyclodextrin grafted with butyl sulfonic acid in aqueous media[J]. Chinese Journal of Catalysis, 2015, 36(8): 1249-1255.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(15)60888-9

https://www.cjcatal.com/EN/Y2015/V36/I8/1249

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