Oxidative desulfurization of dibenzothiophene catalyzed by peroxotungstate on functionalized MCM-41 materials using hydrogen peroxide as oxidant

doi:10.1016/S1872-2067(15)60897-X

Abstract

Abstract:

Catalysts play an important role in oxidative desulfurization, a promising process for producing cleaner fossil fuels for transport. A highly efficient catalyst, Q₄-H₂Se^IV₃W₆, for the oxidative desulfurization of dibenzothiophene (DBT) was reported in 2011. To comprehensively evaluate this catalyst and better understand its recovery, two types of the catalyst were prepared by impregnating Q₄-H₂Se^IV₃W₆on MCM-41 and functionalized MCM-41 materials. In the oxidative desulfurization process catalyzed by these supported catalysts, the conversion of DBT reached 98.7%. The catalytic activities were excellent when Q₄-H₂Se^IV₃W₆ was impregnated on functionalized MCM-41. The results showed that the supported catalysts had excellent reusability. In addition, a mechanism for the catalytic oxidative desulfurization was proposed.

Key words: Dibenzothiophene, Oxidative desulfurization, Peroxotungstate, MCM-41

Dong Xie, Qihui He, Yangyang Su, Tongwei Wang, Renfu Xu, Baixing Hu. Oxidative desulfurization of dibenzothiophene catalyzed by peroxotungstate on functionalized MCM-41 materials using hydrogen peroxide as oxidant[J]. Chinese Journal of Catalysis, 2015, 36(8): 1205-1213.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(15)60897-X

https://www.cjcatal.com/EN/Y2015/V36/I8/1205

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