Chinese Journal of Catalysis ›› 2015, Vol. 36 ›› Issue (9): 1494-1504.DOI: 10.1016/S1872-2067(15)60931-7

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17O solid-state NMR studies of oxygen-containing catalysts

Li Shen, Luming Peng   

  1. Key Laboratory of Mesoscopic Chemistry of MOE and Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, Jiangsu, China
  • Received:2015-04-17 Revised:2015-05-21 Online:2015-08-28 Published:2015-09-26
  • Supported by:

    This work was supported by the National Basic Research Program of China (973 Program, 2013CB934800), the National Natural Science Foundation of China (21222302, 20903056, 21073083), the National Natural Science Foundation of China-Royal Society (NSFC-RS) Joint Project (21111130201), the Program for New Century Excellent Talents in University (NCET-10-0483), and the Fundamental Research Funds for the Central Universities (1124020512).

Abstract:

Oxygen-containing catalysts have a broad range of applications, and it is important to understand the structure-property relationships of these materials. In the past 30 years, 17O NMR spectroscopy, which is sensitive to the local structure of oxygen, has been used to study various catalysts, including non-framework oxides, zeolites, heteropoly acids, layered double hydroxides (LDHs) and metal-organic frameworks (MOFs). The results from these studies have provided rich information on the structure and interactions of oxygen catalysts. This review summarizes significant progress in 17O solid-state NMR studies of oxides and related catalysts.

Key words: 17O, Solid-state nuclear magnetic resonance, Catalyst, Oxide, Hydroxide