Methanol to hydrocarbons reaction over HZSM-22 and SAPO-11: Effect of catalyst acid strength on reaction and deactivation mechanism

doi:10.1016/S1872-2067(15)60953-6

Chinese Journal of Catalysis ›› 2015, Vol. 36 ›› Issue (8): 1392-1402.DOI: 10.1016/S1872-2067(15)60953-6

Methanol to hydrocarbons reaction over HZSM-22 and SAPO-11: Effect of catalyst acid strength on reaction and deactivation mechanism

Jinbang Wang^a,b,d, Jinzhe Li^b, Shutao Xu^b, Yuchun Zhi^b, Yingxu Wei^b, Yanli He^b, Jingrun Chen^b,d, Mozhi Zhang^b,d, Quanyi Wang^b, Wenna Zhang^b,d, Xinqiang Wu^b,d, Xinwen Guo^a, Zhongmin Liu^b,c

a State Key Laboratory of Fine Chemicals, PSU-DUT Joint Center for Energy Research, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China;
b National Engineering Laboratory for Methanol to Olefins, State Energy Low Carbon Catalysis and Engineering R&D Center, Dalian National Laboratory for Clean Energy, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
c State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
d University of Chinese Academy of Sciences, Beijing 100049, China

Received:2015-05-26 Revised:2015-07-09 Online:2015-07-29 Published:2015-07-30
Supported by:
This work was supported by the National Natural Science Foundation of China (201473182, 21273005, 21273230, 21103180).

Abstract

Abstract:

The conversion of methanol to hydrocarbons has been investigated over HZSM-22 and SAPO-11. Both of these catalysts possess one-dimensional 10-ring channels, but have different acidic strengths. Comparison studies and ¹²C/¹³C isotopic switching experiments were conducted to evaluate the influence of the acidic strength of the catalyst on the conversion of methanol, as well as its deactivation mechanism. Although the conversion of methanol proceeded via an alkene methylation-cracking pathway over both catalysts, the acidity of the catalysts had a significant impact on the conversion and product distribution of these reactions. The stability of the catalysts varied with temperature. The catalysts were deactivated at high temperature by the deposition of graphitic coke on their outer surface. Deactivation also occurred at low temperatures a result that the pores of the catalyst were blocked by polyaromatic compounds. The co-reaction of ¹³C-methanol and ¹²C-1-butene confirmed the importance of the acidity of the catalyst on the distribution of the hydrocarbon products.

Key words: HZSM-22, SAPO-11, Methanol-to-hydrocarbon, Acid strength, Mechanism

Jinbang Wang, Jinzhe Li, Shutao Xu, Yuchun Zhi, Yingxu Wei, Yanli He, Jingrun Chen, Mozhi Zhang, Quanyi Wang, Wenna Zhang, Xinqiang Wu, Xinwen Guo, Zhongmin Liu. Methanol to hydrocarbons reaction over HZSM-22 and SAPO-11: Effect of catalyst acid strength on reaction and deactivation mechanism[J]. Chinese Journal of Catalysis, 2015, 36(8): 1392-1402.

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References

[1] Olsbye U, Svelle S, Bjorgen M, Beato P, Janssens T V W, Joensen F, Bordiga S, Lillerud K P. Angew Chem Int Ed, 2012, 51: 5810
[2] Wei Y X, Zhang D Z, Liu Z M, Su B L. Chin J Catal (魏迎旭, 张大治, 刘中民, 苏宝连. 催化学报), 2012, 33: 11
[3] Stöcker M. Microporous Mesoporous Mater, 1999, 29: 3
[4] Tian P, Wei Y X, Ye M, Liu Z M. ACS Catal, 2015, 5: 1922
[5] Hemelsoet K, Van der Mynsbrugge J, De Wispelaere K, Waroquier M, Van Speybroeck V. ChemPhysChem, 2013, 14: 1526
[6] Liang J, Li H Y, Zhao S, Guo W G, Wang R H, Ying M L. Appl Catal, 1990, 64: 31
[7] Koempel H, Liebner W. Stud Surf Sci Catal, 2007, 167: 261
[8] Chang C D. Catal Today, 1992, 13: 103
[9] Yurchak S. Stud Surf Sci Catal, 1988, 36: 251
[10] Topp-Jørgensen J. Stud Surf Sci Catal, 1988, 36: 293
[11] Chen J Q, Bozzano A, Glover B, Fuglerud T, Kvisle S. Catal Today, 2005, 106: 103
[12] Dahl I M, Kolboe S. J Catal, 1996, 161: 304
[13] Dahl I M, Kolboe S. J Catal, 1994, 149: 458
[14] Dahl I, Kolboe S. Catal Lett, 1993, 20: 329
[15] Arstad B, Kolboe S. J Am Chem Soc, 2001, 123: 8137
[16] Song W G, Haw J F, Nicholas J B, Heneghan C S. J Am Chem Soc, 2000, 122: 10726
[17] Wang C M, Wang Y D, Liu H X, Xie Z K, Liu Z P. J Catal, 2010, 271: 386
[18] Hereijgers B P C, Bleken F, Nilsen M H, Svelle S, Lillerud K P, Bjørgen M, Weckhuysen B M, Olsbye U. J Catal, 2009, 264: 77
[19] Xu S T, Zheng A M, Wei Y X, Chen J R, Li J Z, Chu Y Y, Zhang M Z, Wang Q Y, Zhou Y, Wang J B, Deng F, Liu Z M. Angew Chem Int Ed, 2013, 52: 11564
[20] Wulfers M J, Jentoft F C. ACS Catal, 2014, 4: 3521
[21] Li J Z, Wei Y X, Chen J R, Xu S T, Tian P, Yang X F, Li B, Wang J B, Liu Z M. ACS Catal, 2015, 5: 661
[22] Wang C M, Wang Y D, Xie Z K, Liu Z P. J Phys Chem C, 2009, 113: 4584
[23] Bjørgen M, Olsbye U, Petersen D, Kolboe S. J Catal, 2004, 221: 1
[24] Li J Z, Wei Y X, Chen J R, Tian P, Su X, Xu S T, Qi Y, Wang Q Y, Zhou Y, He Y L, Liu Z M. J Am Chem Soc, 2012, 134: 836
[25] Li J Z, Wei Y X, Xu S T, Tian P, Chen J R, Liu Z M. Catal Today, 2014, 226: 47
[26] Svelle S, Joensen F, Nerlov J, Olsbye U, Lillerud K P, Kolboe S, Bjørgen M. J Am Chem Soc, 2006, 128: 14770
[27] Bjorgen M, Svelle S, Joensen F, Nerlov J, Kolboe S, Bonino F, Palumbo L, Bordiga S, Olsbye U. J Catal, 2007, 249: 195
[28] Svelle S, Olsbye U, Joensen F, Bjørgen M. J Phys Chem C, 2007, 111: 17981
[29] Teketel S, Svelle S, Lillerud K-P, Olsbye U. ChemCatChem, 2009, 1: 78
[30] Teketel S, Olsbye U, Lillerud K-P, Beato P, Svelle S. Microporous Mesoporous Mater, 2010, 136: 33
[31] Li J Z, Wei Y X, Liu G Y, Qi Y, Tian P, Li B, He Y L, Liu Z M. Catal Today, 2011, 171: 221
[32] Li J Z, Wei Y X, Qi Y, Tian P, Li B, He Y L, Chang F X, Sun X D, Liu Z M. Catal Today, 2011, 164: 288
[33] Yuen L-T, Zones S I, Harris T V, Gallegos E J, Auroux A. Microporous Mater, 1994, 2: 105
[34] Bleken F, Bjørgen M, Palumbo L, Bordiga S, Svelle S, Lillerud K-P, Olsbye U. Top Catal, 2009, 52: 218
[35] Westgård Erichsen M, Svelle S, Olsbye U. J Catal, 2013, 298: 94
[36] Yang G J, Wei Y X, Xu S T, Chen J R, Li J Z, Liu Z M, Yu J H, Xu R R. J Phys Chem C, 2013, 117: 8214
[37] Guisnet M, Costa L, Ribeiro F R. J Mol Catal A, 2009, 305: 69
[38] Buchholz A, Wang W, Xu M, Arnold A, Hunger M. Microporous Mesoporous Mater, 2002, 56: 267
[39] Li B, Tian P, Qi Y, Zhang L, Xu S T, Su X, Fan D, Liu Z M. Chin J Catal (李冰, 田鹏, 齐越, 张琳, 徐舒涛, 苏雄, 樊栋, 刘中民. 催化学报), 2013, 34: 593
[40] Jiang Y J, Huang J, Dai W L, Hunger M. Solid State Nucl Magn Reson, 2011, 39: 116
[41] Müller M, Harvey G, Prins R. Microporous Mesoporous Mater, 2000, 34: 281
[42] Zheng A M, Huang X J, Wang Q, Zhang H L, Deng F, Liu S B. Chin J Catal (郑安民, 黄信炅, 王强, 张海禄, 邓风, 刘尚斌. 催化学报), 2013, 34: 436
[43] Hunger M, Anderson M W, Ojo A, Pfeifer H. Microporous Mater, 1993, 1: 17
[44] Hunger M. Catal Rev, 1997, 39: 345
[45] Zhang W P, Ma D, Liu X C, Liu X M, Bao X H. Chem Commun, 1999: 1091
[46] Borade R B, Adnot A, Kaliaguine S. Zeolites, 1991, 11: 710
[47] Sousa Z S B, Cesar D V, Henriques C A, Teixeira da Silva V. Catal Today, 2014, 234: 182

Methanol to hydrocarbons reaction over HZSM-22 and SAPO-11: Effect of catalyst acid strength on reaction and deactivation mechanism

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