Ni@Pd core-shell nanoparticles supported on a metal-organic framework as highly efficient catalysts for nitroarenes reduction

doi:10.1016/S1872-2067(15)60940-8

Abstract

Abstract:

Ni@Pd core-shell nanoparticles with a mean particle size of 8-9 nm were prepared by solvothermal reduction of bivalent nickel and palladium in oleylamine and trioctylphosphine. Subsequently, the first-ever deposition of Ni@Pd core-shell nanoparticles having different compositions on a metal-organic framework (MIL-101) was accomplished by wet impregnation in n-hexane. The Ni@Pd/MIL-101 materials were characterized by powder X-ray diffraction, Fourier transform infrared spectroscopy, transmission electron microscopy, and energy-dispersive X-ray spectroscopy and also investigated as catalysts for the hydrogenation of nitrobenzene under mild reaction conditions. At 30 ℃ and 0.1 MPa of H₂ pressure, the Ni@Pd/MIL-101 gives a TOF as high as 375 h^-1 for the hydrogenation of nitrobenzene and is applicable to a wide range of substituted nitroarenes. The exceptional performance of this catalyst is believed to result from the significant Ni-Pd interaction in the core-shell structure, together with promotion of the conversions of aromatics by uncoordinated Lewis acidic Cr sites on the MIL-101 support.

Key words: Nickel, Palladium, Core-shell nanoparticle, Metal-organic framework, Nitroarene, Hydrogenation, Heterogeneous catalysis

Siping Jian, Yingwei Li. Ni@Pd core-shell nanoparticles supported on a metal-organic framework as highly efficient catalysts for nitroarenes reduction[J]. Chinese Journal of Catalysis, 2016, 37(1): 91-97.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(15)60940-8

https://www.cjcatal.com/EN/Y2016/V37/I1/91

References

[1] J. L. Pinilla, A. B. García, K. Philippot, P. Lara, E. J. García-Suárez, M. Millan, Fuel, 2014, 116, 729.
[2] G. Z. Chen, S. J. Wu, H. L. Liu, H. F. Jiang, Y. W. Li, Green Chem., 2013, 15, 230.
[3] B. Z. Yuan, Y. Y. Pan, Y. W. Li, B. L. Yin, H. F. Jiang, Angew. Chem. Int. Ed., 2010, 49, 4054.
[4] F. R. Wang, S. S. Tang, Y. H. Yu, L. F. Wang, B. L .Yin, X H. Li, Chin. J. Catal., 2014, 35, 1921.
[5] M. R. Nabid, Y. Bide, N. Ghalavand, M. Niknezhad, Appl. Organomet. Chem., 2014, 28, 389.
[6] R. Ghosh Chaudhuri, S. Paria, Chem. Rev., 2012, 112, 2373.
[7] Y. Z. Chen, Q. Xu, S. H. Yu, H. L. Jiang, Small, 2015, 11, 71.
[8] P. P. Zhang, Y. B. Hu, B. H. Li, Q. J. Zhang, C. Zhou, H. B. Yu, X. J. Zhang, L. Chen, B. Eichhorn, S. H. Zhou, ACS Catal., 2015, 5, 1335.
[9] Q. Sun, X. Q. Zhang, Y. Wang, A. H. Lu, Chin. J. Catal., 2015, 36, 683.
[10] J. Hermannsdörfer, M. Friedrich, N. Miyajima, R. Q. Albuquerque, S. Kümmel, R. Kempe, Angew. Chem. Int. Ed., 2012, 51, 11473.
[11] S. U. Son, Y. Jang, J. Park, H. B. Na, H. M. Park, H. J. Yun, J. Lee, T. Hyeon, J. Am. Chem. Soc., 2004, 126, 5026.
[12] R. Massard, D. Uzio, C. Thomazeau, C. Pichon, J. L. Rousset, J. C.. Bertolini, J. Catal., 2007, 245, 133.
[13] M. M. Zhang, Z. X. Yan, Q. Sun, J. M. Xie, J. J. Jing, New J. Chem., 2012, 36, 2533.
[14] O. Metin, S. F. Ho, C. Alp, H. Can, M. N. Mankin, M. S. Gültekin, M. F. Chi, S. H. Sun, Nano Res., 2013, 6, 10.
[15] H. S. Wei, X. Y. Liu, A. Q. Wang, L. L. Zhang, B. T. Qiao, X. F. Yang, Y. Q. Huang, S. Miao, J. Y. Liu, T. Zhang, Nat. Commun., 2014, 5, 5634.
[16] K. I. Shimizu, Y. Miyamoto, T. Kawasaki, T. Tanji, Y. Tai, A. Satsuma, J. Phys. Chem. C, 2009, 113, 17803.
[17] W. W. Lin, H. Y. Cheng, J. Ming, Y. C. Yu, F. Y. Zhao, J. Catal., 2012, 291, 149.
[18] W. C. Du, G. Z. Chen, R. F. Nie, Y. W. Li, Z. Y. Hou, Catal. Commun., 2013, 41, 56.
[19] K. Fuku, T. Sakano, T. Kamegawa, K. Mori, H. Yamashita, J. Mater. Chem., 2012, 22, 16243.
[20] E. Kim, H. S. Jeong, B. M. Kim, Catal. Commun., 2014, 45, 25.
[21] J. R. Niu, X. Huo, F. W. Zhang, H. B. Wang, P. Zhao, W. Q. Hu, J. T. Ma, R. Li, ChemCatChem, 2013, 5, 349.
[22] G. Férey, C. Mellot-Draznieks, C. Serre, F. Millange, J. Dutour, S. Surblé, I. Margiolaki, Science, 2005, 309, 2040.
[23] H. L. Liu, Y. W. Li, H. F. Jiang, C. Vargas, R. Luque, Chem. Commun., 2012, 48, 8431.
[24] Y. Y. Pan, B. Z. Yuan, Y. W. Li, D. H. He, Chem. Commun., 2010, 46, 2280.
[25] Y. K. Hwang, D. Y. Hong, J. S. Chang, S. H. Jhung, Y. K. Seo, J. Kim, A. Vimont, M. Daturi, C. Serre, G. Férey, Angew. Chem. Int. Ed., 2008, 47, 4144.
[26] M. M. Zhang, Z. X. Yan, J. M. Xie, Electrochim. Acta, 2012, 77, 237.
[27] Y. Pan, H. Y. Bai, L. Pan, Y. D. Li, M. C. Tamargo, M. Sohel, J. R.. Lombardi, J. Mater. Chem., 2012, 22, 23593.
[28] Y. Wu, D. S. Wang, Z. Q. Niu, P. C. Chen, G. Zhou, Y. D. Li, Angew. Chem. Int. Ed., 2012, 51, 12524.
[29] P. Wang, F. W. Zhang, Y. Long, M. Xie, R. Li, J. T. Ma, Catal. Sci. Technol., 2013, 3, 1618.
[30] Z. K. Zhao, H. L. Yang, Y. Li, RSC Adv., 2014, 4, 22669.