Ruthenium nanoparticles supported on mesoporous MCM-41 as an efficient and reusable catalyst for selective oxidation of arenes under ultrasound irradiation

doi:10.1016/S1872-2067(15)61001-4

Abstract

Abstract:

Mesoporous MCM-41 was used as a support for the uniform dispersion of ruthenium nanoparticles having an average particle size of ~5 nm. The obtained nanocomposite, MCM-41-Ru, was characterized using inductively coupled plasma, transmission electron microscopy, energy dispersive X-ray analysis, X-ray diffraction, and BET surface area measurements. The material was employed as an efficient and recyclable catalyst in the ultrasound-assisted oxidation of arenes. It was observed that ultrasound irradiation in combination with KBrO₃ as the oxidant, in the presence of MCM-41-Ru nanoparticles, accelerates the oxidation reaction to afford the desired products in good yields. The recovered catalyst retained activity for successive runs, with a continuous change in the nature of its active sites.

Key words: Nanoparticle, Ultrasound, Ruthenium, Arene oxidation, MCM-41

Alireza Khorshidi. Ruthenium nanoparticles supported on mesoporous MCM-41 as an efficient and reusable catalyst for selective oxidation of arenes under ultrasound irradiation[J]. Chinese Journal of Catalysis, 2016, 37(1): 153-158.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(15)61001-4

https://www.cjcatal.com/EN/Y2016/V37/I1/153

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