Selective reduction of carbon dioxide to carbon monoxide over Au/CeO2 catalyst and identification of reaction intermediate

doi:10.1016/S1872-2067(16)62538-X

Abstract

Abstract:

CO₂ selective reduction to CO with H₂ over a CeO₂-supported nano-Au catalyst at atmospheric pressure was investigated. A high CO₂ conversion, approaching the thermodynamic equilibrium value, and nearly 100% CO selectivity were obtained. The surface formate intermediates generated during the reverse water-gas shift reaction at 400℃ were identified using in situ diffuse-reflectance infrared Fourier-transform spectroscopy. The formate consumption to give CO and H₂O, determined using mass spectrometry, indicated that the reaction proceeded via an associative formate mechanism; this contributes to the high Au/CeO₂ catalytic activity at low temperatures.

Key words: CO₂ reduction, Au/CeO₂ catalyst, Carbon monoxide, Formate intermediate, In situ DRIFT spectroscopy

Xiaobing Zhu, Xin Qu, Xiaosong Li, Jinglin Liu, Jianhao Liu, Bin Zhu, Chuan Shi. Selective reduction of carbon dioxide to carbon monoxide over Au/CeO₂ catalyst and identification of reaction intermediate[J]. Chinese Journal of Catalysis, 2016, 37(12): 2053-2058.

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Selective reduction of carbon dioxide to carbon monoxide over Au/CeO₂ catalyst and identification of reaction intermediate

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