Olefin oligomerization via new and efficient Brönsted acidic ionic liquid catalyst systems

doi:10.1016/S1872-2067(18)63071-2

Abstract

Abstract:

Olefin oligomerization reaction catalyzed by new catalyst systems (a Brönsted-acidic ionic liquid as the main catalyst and tricaprylylmethylammonium chloride as the co-catalyst) has been investigated. The synthesized Brönsted acidic ionic liquids were characterized by Fourier transform infrared spectroscopy (FT-IR), ultraviolet-visible spectroscopy (UV), ¹H nuclear magnetic resonance (NMR), and ¹³C NMR to analyze their structures and acidities. The influence of different ionic liquids, ionic liquid loading, different co-catalysts, catalyst ratios (mole ratio of ionic liquid to co-catalyst), reaction time, pressure, temperature, solvent, source of reactants, and the recycling of catalyst systems was studied. Among the synthesized ionic liquids, 1-(4-sulfonic acid)butyl-3-hexylimidazolium hydrogen sulfate ([HIMBs]HSO₄) exhibited the best catalytic activity under the tested reaction conditions. The conversion of isobutene and selectivity of trimers were 83.21% and 35.80%, respectively, at the optimum reaction conditions. Furthermore, the catalyst system can be easily separated and reused; a feasible reaction mechanism is proposed on the basis of the distribution of experimental products.

Key words: Brönsted acidic ionic liquid, Olefin, Oligomerization, Catalysis, Co-catalyst

Guoqin Wang, Heyuan Song, Ruiyun Li, Zhen Li, Jing Chen. Olefin oligomerization via new and efficient Brönsted acidic ionic liquid catalyst systems[J]. Chinese Journal of Catalysis, 2018, 39(6): 1110-1120.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(18)63071-2

https://www.cjcatal.com/EN/Y2018/V39/I6/1110

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