Incorporation of flexible ionic polymers into a Lewis acid-functionalized mesoporous silica for cooperative conversion of CO2 to cyclic carbonates

doi:10.1016/S1872-2067(19)63340-1

Abstract

Abstract: A rational integration of multiple reactive centers into a combined unit to facilitate their cooperative effects is a smart approach for accelerating the catalytic activity. Here, to achieve this goal, linear imidazolium-based ionic polymers were confined into the nanopores of mesoporous silica nanospheres anchored with homogeneously distributed zinc salts. Owing to the flexible character and the reinforced cooperative effects of the ionic liquid (nucleophile) and zinc species (Lewis acid) in the confined mesoporous structure, the resultant composite exhibited dramatically improved catalytic performance in the cycloaddition of CO₂ with epoxides to form cyclic carbonates. This was in contrast to that observed for the individual catalytic components. Moreover, such a solid catalyst could be easily recovered and reused four times without a significant loss of activity.

Key words: Mesoporous silica, Flexible ionic polymer, Cooperative effects, CO₂ utilization, Heterogeneous catalysis

Ruqun Guan, Xiaoming Zhang, Fangfang Chang, Nan Xue, Hengquan Yang. Incorporation of flexible ionic polymers into a Lewis acid-functionalized mesoporous silica for cooperative conversion of CO₂ to cyclic carbonates[J]. Chinese Journal of Catalysis, 2019, 40(12): 1874-1883.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(19)63340-1

https://www.cjcatal.com/EN/Y2019/V40/I12/1874

References

[1] Q. Liu, L. P. Wu, R. Jackstell, M. Beller, Nat. Commun., 2015, 6, 5933.
[2] M. Aresta, A. Dibenedetto, A. Angelini, Chem. Rev., 2014, 114, 1709-1742.
[3] C. Martín, G. Fiorani, A. W. Kleij, ACS Catal., 2015, 5, 1353-1370.
[4] A. J. Hunt, E. H. K. Sin, R. Marriott, J. H. Clark, ChemSusChem, 2010, 3, 306-322.
[5] H. Büttner, L. Longwitz, J. Steinbauer, C. Wulf, T. Werner, Top. Curr. Chem., 2017, 375, 50.
[6] R. R. Shaikh, S. Pornpraprom, V. D'Elia, ACS Catal., 2018, 8, 419-450.
[7] A. Decortes, A. M. Castilla, A. W. Kleij, Angew. Chem. Int. Ed., 2010, 49, 9822-9837.
[8] T. Ema, Y. Miyazaki, J. Shimonishi, C. Maeda, J. Hasegawa, J. Am. Chem. Soc., 2014, 136, 15270-15279.
[9] V. D'Elia, H. l. Dong, A. J. Rossini, C. M. Widdifield, Sai V. C. Vummaleti, Y. Minenkov, A. Poater, E. Abou-Hamad, J. D. A. Pelletier, L. Cavallo, L. Emsley, J. M. Basset, J. Am. Chem. Soc., 2015, 137, 7728-7739.
[10] A. Barthel, Y. Saih, M. Gimenez, J. D. A. Pelletier, F. E. Kühn, V. D'Elia, J. M. Basset, Green Chem., 2016,18, 3116-3123.
[11] L. H. Yang, H. M. Wang, ChemSusChem, 2014, 7, 962-998.
[12] B. H. Xu, J. Q. Wang, J. Sun, Y. Huang, J. P. Zhang, X. P. Zhang, S. J. Zhang, Green Chem., 2015, 17, 108-122.
[13] F. W. Li, L. F. Xiao, C. G. Xia, B. Hu, Tetrahedron Lett., 2004, 45, 8307-8310.
[14] K. Wu, T. Su, D. M. Hao, W. P. Liao, Y. C. Zhao, W. Z. Ren, C. L. Deng, H. Y. Lv, Chem. Commun., 2018, 54, 9579-9582.
[15] M. North, B. D. Wang, C. Young, Energy Environ. Sci., 2011, 4, 4163-4170.
[16] O. V. Zalomaeva, A. M. Chibiryaev, K. A. Kovalenko, O. A. Kholdeeva, B. S. Balzhinimaev, V. P. Fedin, J. Catal., 2013, 298, 179-185.
[17] C. A. Trickett, A. Helal, B. A. Al-Maythalony, Z. H. Yamani, K. E. Cordova, O. M. Yaghi, Nat. Rev. Mater., 2017, 2, 17045.
[18] H. M. He, J. A. Perman, G. S. Zhu, S. Q. Ma, Small, 2016, 12, 6309-6324.
[19] K. Huang, J. Y. Zhang, F. J. Liu, S. Dai, ACS Catal., 2018, 8, 9079-9102.
[20] Y. Xie, T. T. Wang, X. H. Liu, K. Zou, M. W. Q. Deng, Nat. Commun., 2013, 4, 1960.
[21] J. Chen, M. M. Zhong, L. Tao, L. N. Liu, S. Jayakumar, C. Z. Li, H. Li, Q. H. Yang, Green Chem., 2018, 20, 903-911.
[22] X. Y. Ma, B. Zou, M. H. Cao, S. L. Chen, C. W. Hu, J. Mater. Chem. A, 2014, 2, 18360-18366.
[23] F. D. Bobbink, D. Vasilyev, M. Hulla, S. Chamam, F. Menoud, G. Laurenczy, S. Katsyuba, P. J. Dyson, ACS Catal., 2018, 8, 2589-2594.
[24] G. K. Cui, J. J. Wang, S. J. Zhang, Chem. Soc. Rev., 2016, 45, 4307-4339.
[25] Z. Z. Yang, Y. N. Zhao, L. N. He, RSC Adv., 2011, 1, 545-567.
[26] F. D. Bobbink, P. J. Dyson, J. Catal., 2016, 343, 52-61.
[27] X. P. Zhang, X. C. Zhang, H. F. Dong, Z. J. Zhao, S. J. Zhang, Y. Huang, Energy Environ. Sci., 2012, 5, 6668-6681.
[28] M. V. Zakharova, F. Kleitz, F. G. Fontaine, ChemCatChem, 2017, 9, 1886-1890.
[29] X. F. Wang, N. G. Akhmedov, Y. H. Duan, D. Luebke, B. Y. Li, J. Mater. Chem. A, 2013, 1, 2978-2982.
[30] Q. Su, Y. Q. Qi, X. Q. Yao, W. G. Cheng, L. Dong, S. S. Chen, S. J. Zhang, Green Chem., 2018, 20, 3232-3241.
[31] W. Zhang, Q. X. Wang, H. L. Wu, P. Wu, M. Y. He, Green Chem., 2014, 16, 4767-4774.
[32] X. C. Wang, Y. Zhou, Z. J. Guo, G. J. Chen, J. Li, Y. M. Shi, Y. Q. Liu, J. Wang, Chem. Sci., 2015, 6, 6916-6924.
[33] Y. Liu, W. G. Cheng, Y. Q. Zhang, J. Sun, S. J. Zhang, Green Chem., 2017, 19, 2184-2193.
[34] W. L. Wang, C. Y. Li, L. Yan, Y. Q. Wang, M. Jiang, Y. J. Ding, ACS Catal., 2016, 6, 6091-6100.
[35] M. L. Ding, H. L. Jiang, ACS Catal., 2018, 8, 3194-3201.
[36] B. Aguila, Q. Sun, X. L. Wang, E. O'Rourke, A. M. Al-Enizi, A. Nafady, S. Q. Ma, Angew. Chem. Int. Ed., 2018, 57, 10107-10111.
[37] Q. Sun, B. Aguila, J. A. Perman, N. T. K. Nguyen, S. Q. Ma, J. Am. Chem. Soc., 2016, 138, 15790-15796.
[38] S. Jayakumar, H. Li, L. Tao, C. Z. Li, L. N. Liu, J. Chen, Q. H. Yang, ACS Sustainable Chem. Eng., 2018, 6, 9237-9245.
[39] Y. J. Chen, R. C. Luo, Q. H. Xu, J. Jiang, X. T. Zhou, H. B. Ji, ChemSusChem, 2017, 10, 2534-2541.
[40] W. L. Wang, Y. Q. Wang, C. Y. Li, L. Yan, M. Jiang, Y. J. Ding, ACS Sustainable Chem. Eng., 2017, 5, 4523-4528.
[41] C. Y. Li, W. L. Wang, L. Yan, Y. Q. Wang, M. Jiang, Y. J. Ding, J. Mater. Chem. A, 2016, 4, 16017-16027.
[42] B. Li, S. Y. Bai, X. F. Wang, M. M. Zhong, Q. H. Yang, C. Li, Angew. Chem. Int. Ed., 2012, 51, 11517-11521.
[43] H. Chang, Q. S. Li, X. M. Cui, H. X. Wang, C. Z. Qiao, Z. W. Bu, T. Lin, Mol. Catal., 2018, 449, 25-30.
[44] L. Y. Jing, X. M. Zhang, R. Q. Guan, H. Q. Yang, Catal. Sci. Technol., 2018, 8, 2304-2311.
[45] J. Wei, Z. K. Sun, W. Luo, Y. H. Li, A. A. Elzatahry, A. M. Al-Enizi, Y. H. Deng, D. Y. Zhao, J. Am. Chem. Soc., 2017, 139, 1706-1713.
[46] J. Liu, S. Z. Qiao, J. S. Chen, X. W. Lou, Chem. Commun., 2011, 47, 12578-12591.
[47] T. Y. Cheng, Q. K. Zhao, D. C. Zhang, G. H. Liu, Green Chem., 2015, 17, 2100-2122.
[48] X. M. Zhang, S. M. Lu, M. M. Zhong, Y. P. Zhao, Q. H. Yang, Chin. J. Catal., 2015, 36, 168-174.
[49] Y. Xie, Z. F. Zhang, T. Jiang, J. L. He, B. X. Han, T. B. Wu, K. L. Ding, Angew. Chem. Int. Ed., 2007, 46, 7255-7258.
[50] J. Peng, Y. Yao, X. M. Zhang, C. Li, Q. H. Yang, Chem. Commun., 2014, 50, 10830-10833.
[51] W. L. Wang, L. F. Cui, P. Sun, L. J. Shi, C. T. Yue, F. W. Li, Chem. Rev., 2018, 118, 9843-9929.
[52] L. F. Xiao, F. W. Li, J. J. Peng, C. G. Xia, J. Mol. Catal. A, 2006, 253, 265-269.

Incorporation of flexible ionic polymers into a Lewis acid-functionalized mesoporous silica for cooperative conversion of CO₂ to cyclic carbonates

PDF (PC)

Knowledge

Supporting Information

Abstract

Cite this article

share this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

[1]	Abhishek R. Varma, Bhushan S. Shrirame, Sunil K. Maity, Deepti Agrawal, Naglis Malys, Leonardo Rios-Solis, Gopalakrishnan Kumar, Vinod Kumar. Recent advances in fermentative production of C4 diols and their chemo-catalytic upgrading to high-value chemicals [J]. Chinese Journal of Catalysis, 2023, 52(9): 99-126.
[2]	Meng Zhao, Jing Xu, Shuyan Song, Hongjie Zhang. Core/yolk-shell nanoreactors for tandem catalysis [J]. Chinese Journal of Catalysis, 2023, 50(7): 83-108.
[3]	Si-Yuan Xia, Qi-Yuan Li, Shi-Nan Zhang, Dong Xu, Xiu Lin, Lu-Han Sun, Jingsan Xu, Jie-Sheng Chen, Guo-Dong Li, Xin-Hao Li. Size-dependent electronic interface effect of Pd nanocube-based heterojunctions on universally boosting phenol hydrogenation reactions [J]. Chinese Journal of Catalysis, 2023, 49(6): 180-187.
[4]	Runze Liu, Xue Shao, Chang Wang, Weili Dai, Naijia Guan. Reaction mechanism of methanol-to-hydrocarbons conversion: Fundamental and application [J]. Chinese Journal of Catalysis, 2023, 47(4): 67-92.
[5]	Changcheng Wei, Wenna Zhang, Kuo Yang, Xiu Bai, Shutao Xu, Jinzhe Li, Zhongmin Liu. An efficient way to use CO₂ as chemical feedstock by coupling with alkanes [J]. Chinese Journal of Catalysis, 2023, 47(4): 138-149.
[6]	Long Jiao, Hai-Long Jiang. Metal-organic frameworks for catalysis: Fundamentals and future prospects [J]. Chinese Journal of Catalysis, 2023, 45(2): 1-5.
[7]	Chao Nie, Xiangdong Long, Qi Liu, Jia Wang, Fei Zhan, Zelun Zhao, Jiong Li, Yongjie Xi, Fuwei Li. Facile fabrication of atomically dispersed Ru-P-Ru ensembles for efficient hydrogenations beyond isolated single atoms [J]. Chinese Journal of Catalysis, 2023, 45(2): 107-119.
[8]	Xuefei Weng, Shuangli Yang, Ding Ding, Mingshu Chen, Huilin Wan. Applications of in-situ wide spectral range infrared absorption spectroscopy for CO oxidation over Pd/SiO₂ and Cu/SiO₂ catalysts [J]. Chinese Journal of Catalysis, 2022, 43(8): 2001-2009.
[9]	Zixuan Zhou, Peng Gao. Direct carbon dioxide hydrogenation to produce bulk chemicals and liquid fuels via heterogeneous catalysis [J]. Chinese Journal of Catalysis, 2022, 43(8): 2045-2056.
[10]	Chunpeng Wang, Zhe Wang, Shanjun Mao, Zhirong Chen, Yong Wang. Coordination environment of active sites and their effect on catalytic performance of heterogeneous catalysts [J]. Chinese Journal of Catalysis, 2022, 43(4): 928-955.
[11]	Hui Chen, Bo Zhang, Xiao Liang, Xiaoxin Zou. Light alloying element-regulated noble metal catalysts for energy-related applications [J]. Chinese Journal of Catalysis, 2022, 43(3): 611-635.
[12]	Teera Chantarojsiri, Tassaneewan Soisuwan, Pornwimon Kongkiatkrai. Toward green syntheses of carboxylates: Considerations of mechanisms and reactions at the electrodes for electrocarboxylation of organohalides and alkenes [J]. Chinese Journal of Catalysis, 2022, 43(12): 3046-3061.
[13]	Tao Zhang, Xiaochi Han, Nhat Truong Nguyen, Lei Yang, Xuemei Zhou. TiO₂-based photocatalysts for CO₂ reduction and solar fuel generation [J]. Chinese Journal of Catalysis, 2022, 43(10): 2500-2529.
[14]	Xiaoling Liu, Lei Chen, Hongzhong Xu, Shi Jiang, Yu Zhou, Jun Wang. Straightforward synthesis of beta zeolite encapsulated Pt nanoparticles for the transformation of 5-hydroxymethyl furfural into 2,5-furandicarboxylic acid [J]. Chinese Journal of Catalysis, 2021, 42(6): 994-1003.
[15]	Zhifeng Dai, Yongquan Tang, Fei Zhang, Yubing Xiong, Sai Wang, Qi Sun, Liang Wang, Xiangju Meng, Leihong Zhao, Feng-Shou Xiao. Combination of binary active sites into heterogeneous porous polymer catalysts for efficient transformation of CO₂ under mild conditions [J]. Chinese Journal of Catalysis, 2021, 42(4): 618-626.