On the comparable activity in plasmonic photocatalytic and thermocatalytic oxidative homocoupling of alkynes over prereduced copper ferrite

doi:10.1016/S1872-2067(19)63418-2

Abstract

Abstract: Despite of extensive attention on the copper-based heterogeneous oxidative homocoupling of alkynes (OHA) to 1,3-diynes, the photocatalytic OHA is scarcely investigated. By screening copper-containing spinel catalysts, we discovered that a prereduced copper ferrite (CuFe₂O₄) not only can catalyze the thermocatalytic OHA but also is efficient for the photocatalytic OHA under visible light irradiation. It is found that the sol-gel combustion (SG) method and the partial reduction at 250℃ can result in the optimal CuFe₂O₄-SG-250 catalyst showing high activity and stability. Surface oxidized Cu₂O is evidenced to be the active species for the thermocatalytic OHA, whereas metallic copper nanopaticles (CuNPs) are identified as the active sites for the photocatalytic OHA. The efficiency of photocatalytic OHA at ambient temperature is comparable to that of thermocatalytic OHA at 120℃, and the CuFe₂O₄-SG-250 catalyst can be magnetically separated and reused at least five times. The localized surface plasmon resonance effect of CuNPs contributes to visible light-induced photocatalytic OHA.

Key words: Alkyne, Homocoupling, Copper ferrite, Copper nanoparticles, Surface plasmon resonance

Ying Zhu, Nan Deng, Meiqing Feng, Peng Liu. On the comparable activity in plasmonic photocatalytic and thermocatalytic oxidative homocoupling of alkynes over prereduced copper ferrite[J]. Chinese Journal of Catalysis, 2019, 40(10): 1505-1515.

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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(19)63418-2

https://www.cjcatal.com/EN/Y2019/V40/I10/1505

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