Catalytic dehydrogenation of formic acid over palladium nanoparticles immobilized on fibrous mesoporous silica KCC-1

doi:10.1016/S1872-2067(19)63303-6

Abstract

Abstract: Uniform Pd nanoparticles immobilized on N-(3-trimethoxysilylpropyl)diethylenetriamine (PDETA)-functionalized fibrous silica KCC-1 (Pd/KCC-1-PDETA) were prepared with a mean Pd particle size of 2.8 nm. After characterization using powder X-ray diffraction, X-ray photoelectron spectroscopy, and N₂ adsorption-desorption isotherms, Pd/KCC-1-PDETA was used as catalyst for additive-free dehydrogenation of formic acid to produce H₂. Pd nanoparticle catalysts supported on two other mesoporous silica materials (MSF and KIT-6) were also synthesized to examine how the support affects the reaction. Among the three catalysts, Pd/KCC-1-PDETA exhibited significant catalytic activity (a turnover frequency of 332 h^-1 at 323 K and 100% selectivity towards hydrogen), owing to the unique fibrous morphology of KCC-1 and the presence of amine groups that reduced the Pd particle size and improved the access of reactant to the catalytically active Pd sites. The influence of Pd loading (2-10 wt.%), reaction temperature, and reaction time was also examined for the dehydrogenation reaction. Pd/KCC-1-PDETA was recovered easily after the reaction and showed good reusability up to five times without any significant loss in catalytic performance.

Key words: Fibrous nanosilica, KCC-1, Palladium nanoparticles, Hydrogen storage, Formic acid dehydrogenation

Siqian Zhang, Yingjie Qian, Wha-Seung Ahn. Catalytic dehydrogenation of formic acid over palladium nanoparticles immobilized on fibrous mesoporous silica KCC-1[J]. Chinese Journal of Catalysis, 2019, 40(11): 1704-1712.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(19)63303-6

https://www.cjcatal.com/EN/Y2019/V40/I11/1704

References

[1] K. Fujita, R. Kawahara, T. Aikawa, R. Yamaguchi, Angew. Chem. Int. Ed., 2015, 54, 9057-9060.
[2] T. Umegaki, A. Seki, Q. Xu, Y. Kojima, J. Alloys Compd., 2014, 588, 615-621.
[3] M. Grasemann, G. Laurenczy, Energy Environ. Sci., 2012, 5, 8171-8181.
[4] S. Fukuzumi, T. Kobayashi, T. Suenobu, J. Am. Chem. Soc., 2010, 132, 1496-1497.
[5] Y. Chen, Q. L. Zhu, N. Tsumori, Q. Xu, J. Am. Chem. Soc., 2015, 137, 106-109.
[6] F. Z. Song, Q. L. Zhu, N. Tsumori, Q. Xu, ACS Catal., 2015, 5, 5141-5144.
[7] M. Ojeda, E. Iglesia, Angew. Chem. Int. Ed., 2009, 48, 4800-4803.
[8] S. Zhang, Ö. Metin, D. Su, S. Sun, Angew. Chem. Int. Ed., 2013, 52, 3681-3684.
[9] Y. L. Qin, J. Wang, F. Z. Meng, L. M. Wang, X. B. Zhang, Chem. Com-mun., 2013, 49,10028-10030.
[10] Z. L. Wang, J. M. Yan, Y. Ping, H. L. Wang, W. T. Zheng, Q. Jiang, Angew. Chem. Int. Ed., 2013, 52, 4406-4409.
[11] M. H. Jin, D. Oh, J. H. Park, C. B. Lee, S. W. Lee, J. S. Park, K. Y. Lee, D. W. Lee, Sci. Rep., 2016, 6, 33502/1-33502/12.
[12] D. W. Lee, M. H. Jin, J. C. Park, C. B. Lee, D. Oh, S. W. Lee, J. W. Park, J. S. Park, Sci. Rep., 2015, 5, 15931/1-15931/11.
[13] M. Navlani-García, M. Martis, D. Lozano-Castelló, D. Cazor-la-Amorós, K. Moribc, H. Yamashita, Catal. Sci. Technol., 2015, 5, 364-371.
[14] Z. S. Qureshi, P. B. Sarawade, M. Albert, V. D'Elia, M. N. Hedhili, K. Kçhler, J. M. Basset, ChemCatChem, 2015, 7, 635-642.
[15] N. Bayal, B. Singh, R. Singh, V. Polshettiwar, Sci. Rep., 2016, 6, 24888-24899.
[16] E. Febriyanti, V. Suendo, R. R. Mukti, A. Prasetyo, A. F. Arifin, M. A. Akbar, S. Triwahyono, I. N. Marsih, Ismunandar, Langmuir, 2016, 32, 5802-5811.
[17] A. Fihri, M. Bouhrara, U. Patil, D. Cha, Y. Saih, V. Polshettiwar, ACS Catal., 2012, 2, 1425-1431.
[18] X. Le, Z. Dong, Y. Liu, Z. Jin, T. Huy, M. Le, J. Ma, J. Mater. Chem. A, 2014, 2, 19696-19706.
[19] A. N. Chermahini, F. Shahangi, H. A. Dabbagh, M. Saraji, RSC Adv., 2016, 6, 33804-33810.
[20] K. Yu, X. Zhang, H. Tong, X. Yan, S. Liu, Mater. Lett., 2013, 106, 151-154.
[21] U. Patil, A. Fihri, A. Emwas, V. Polshettiwar, Chem. Sci., 2012, 3, 2224-2229.
[22] S. H. Joo, J. Y. Park, C. K. Tsung, Y. Yamada, P. Yang, G. A. Somorjai, Nat. Mater., 2009, 8, 126-131.
[23] C. K. P. Neeli, Y. M. Chung, W. S. Ahn, ChemCatChem, 2017, 9, 4570-4579.
[24] B. Singh, V. Polshettiwar, J. Mater. Chem. A, 2016, 4, 7005-7019.
[25] M. Dhiman, B. Chalke, V. Polshettiwar, ACS Sustainable Chem. Eng., 2015, 3, 3224-3230.
[26] M. Bouhrara, C. Ranga, A. Fihri, R. R. Shaikh, P. Sarawade, A. H. Emwas, M. N. Hedhili, V. Polshettiwar, ACS Sustainable Chem. Eng., 2013, 1, 1192-1199.
[27] M. Martis, K. Mori, K. Fujiwara, W. S. Ahn, H. Yamashita, J. Phys. Chem. C, 2013, 117, 22805-22810.
[28] X. Chen, G. Wu, J. Chen, X. Chen, Z. Xie, X. Wang, J. Am. Chem. Soc., 2011, 133, 3693-3695.
[29] S. Akbayrak, Y. Tonbul, S. Özkar, Appl. Catal. B, 2017, 206, 384-392.
[30] M. Zacharska, L. G. Bulusheva, A. S. Lisitsyn, S. Beloshapkin, Y. Guo, A. L. Chuvilin, E. V. Shlyakhova, O. Y. Podyacheva, J. J. Leahy, A. V. Okotrub, D. A. Bulushev, ChemSusChem, 2017, 10, 720-730.
[31] S. T. Gao, W. Liu, C. Feng, N. Z. Shang, C. Wang, Catal. Sci. Technol., 2016, 6, 869-874.
[32] Q. Liu, X. Yang, Y. Huang, S. Xu, X. Su, X. Pan, J. Xu, A. Wang, C. Liang, X. Wang, T. Zhang, Energy Environ. Sci., 2015, 8, 3204-3207.
[33] D. W. Lee, M. H. Jin, J. H. Park, Y. J. Lee, Y. C. Choi, J. C. Park, D. H. Chun, ACS Sustainable Chem. Eng., 2018, 6, 12241-12250.
[34] C. Cui, Y. Tang, M. A. Ziaee, D. Tian, R. Wang, ChemCatChem, 2018, 10, 1431-1437.
[35] J. Li, W. Chen, H. Zhao, X. Zheng, L. Wu, H. Pan, J. Zhu, Y. Chen, J. Lu, J. Catal., 2017, 352, 371-381.
[36] Z. L. Wang, J. M. Yan, H. L. Wang, Y. Ping, Q. Jiang, J. Mater. Chem. A, 2013, 1, 12721-12725.
[37] J. P. Zhou, J. Zhang, X. H. Dai, X. Wang, S. Y. Zhang, Int. J. Hydrogen Energy, 2016, 41, 22059-22066.
[38] Q. L. Zhu, N. Tsumori, Q. Xu, Chem. Sci., 2014, 5, 195-199.
[39] H. M. Dai, B. Q. Xia, L. Wen, C. Du, J. Su, W. Luo, G. Z. Cheng, Appl. Catal. B, 2015, 165, 57-62.
[40] A. Bulut, M. Yurderi, Y. Karatas, M. Zahmakiran, H. Kivrak, M. Gulcan, M. Kaya, Appl. Catal. B, 2015, 164, 324-333.
[41] K. Tedsree, T. Li, S. Jones, C. W. A. Chan, K. M. K. Yu, P. A. J. Bagot, E. A. Marquis, G. D. W. Smith, S. C. E. Tsang, Nat. Nanotechnol., 2011, 6, 302-307.
[42] Ö. Metin, X. Sun, S. Sun, Nanoscale, 2013, 5, 910-912.
[43] S. Zhang, Y. R. Lee, H. J. Jeon, W. S. Ahn, Y. M. Chung, Mater. Lett., 2018, 215, 211-213.
[44] A. Bulut, M. Yurderi, Y. Karatas, Z. Say, H. Kivrak, M. Kaya, M. Gulcan, E. Ozensoy, M. Zahmakiran, ACS Catal., 2015, 5, 6099-6110.
[45] K. Mori, M. Dojo, H. Yamashita, ACS Catal., 2013, 3, 1114-1119.
[46] M. H. Jin, J. H. Park, D. Oh, S. W. Lee, J. S. Park, K. Y. Lee, D. W. Lee, Int. J. Hydrogen Energy, 2018, 43, 1451-1458.
[47] Y. Huang, J. Xu, T. Long, Q. Shuai, Q. Li, J. Nanosci. Nanotechnol., 2017, 17, 3798-3802.
[48] D. W. Lee, M. H. Jin, Y. J. Lee, J. H. Park, C. B. Lee, J. S. Park, Sci. Rep., 2016, 6, 26474/1-26474/9.
[49] Z. L. Wang, J. M. Yan, H. L. Wang, Y. Ping, Q. Jiang, J. Mater. Chem. A, 2013, 1, 12721-12725.
[50] Z. L. Wang, H. L. Wang, J. M. Yan, Y. Ping, S. I. O, S. J. Li, Q. Jiang, Chem. Commun., 2014, 50, 2732-2734.
[51] Z. L. Wang, Y. Ping, J. M. Yan, H. L. Wang, Q. Jiang, Int. J. Hydrogen Energy, 2014, 39, 4850-4856.
[52] Z. L. Wang, J. M. Yan, Y. F. Zhang, Y. Ping, H. L. Wang, Q. Jiang, Na-noscale, 2014, 6, 3073-3077.
[53] S. Jones, J. Qu, K. Tedsree, X. Q. Gong, S. C. E. Tsang, Angew. Chem. Int. Ed., 2012, 51, 11275-11278.