Hydrogen transfer reaction contributes to the dynamic evolution of zeolite-catalyzed methanol and dimethyl ether conversions: Insight into formaldehyde

doi:10.1016/S1872-2067(22)64194-9

Chinese Journal of Catalysis ›› 2023, Vol. 46: 11-27.DOI: 10.1016/S1872-2067(22)64194-9

• Articles • Previous Articles Next Articles

Hydrogen transfer reaction contributes to the dynamic evolution of zeolite-catalyzed methanol and dimethyl ether conversions: Insight into formaldehyde

Shanfan Lin^a^,^c, Yuchun Zhi^a, Wenna Zhang^a, Xiaoshuai Yuan^d, Chengwei Zhang^a^,^c, Mao Ye^a, Shutao Xu^a, Yingxu Wei^a^,^*(), Zhongmin Liu^a^,^b^,^c^,^*()

^aNational Engineering Research Center of Lower-Carbon Catalysis Technology, Dalian National Laboratory for Clean Energy, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China
^bState Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China
^cUniversity of Chinese Academy of Sciences, Beijing 100049, China
^dResearch Center for Energy Strategy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China

Received:2022-09-26 Accepted:2022-11-10 Online:2023-03-18 Published:2023-02-21
Contact: *E-mail: liuzm@dicp.ac.cn (Z. Liu), weiyx@dicp.ac.cn (Y. Wei)
About author:Yingxu Wei received her PhD in Dalian Institute of Chemical Physics (DICP), Chinese Academy of Sciences (CAS) in 2001. During her service at the Applied Catalysis Laboratory of DICP since graduation, she conducted the postdoctoral study at University of Namur (Belgium) from 2003 to 2004. She has been the group leader of Catalysis and New Catalytic Reactions in National Engineering Laboratory of Methanol to Olefins since 2009 and was promoted to professor in 2011. Over the years, Prof. Wei has undertaken a number of key academic research projects commissioned by NSFC, CAS, MOST, PetroChina and other organizations. She has been involved in the researches on heterogeneous catalysis, methanol to olefins, catalysts and processes of hydrocarbon conversion, and catalytic conversion of methanol and methane derivatives. Over 110 academic papers authored by Prof. Wei have been published in scientific journals home and abroad and more than 60 patents have been applied and granted. She gained the national special support plan for high level talents. She is on the editorial board of the Chinese Journal of Catalysis and works as the editor of Microporous and Mesoporous Materials.
Prof. Zhongmin Liu is the Director of Dalian Institute of Chemical Physics (DICP) and Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences (CAS); Director of National Engineering Laboratory for Methanol to Olefins and National Energy Low-carbon Catalysis and Engineering R&D Center.
Prof. Liu has long been working with the catalysis research, process development, and technology transfer in energy conversion and utilization, and made significant achievements. In 2006, as a leading scientist, Professor Liu, together with partners and his colleagues, finished the first industrial demonstration test of methanol to olefin process, named as DMTO. Based on DMTO technology the world’s first commercial unit of MTO process was constructed and started to operate by Shenhua group in 2010, which was an important progress for coal to chemicals, and provides a new chance for the substitution of oil by coal. So far, DMTO technology has been licensed to 31 units with a total olefins production capacity of 20.25 Mt/a. And 16 commercial DMTO units have been put into stream with olefins production capacity of 9.30 Mt/a. This breakthrough leads coal to olefins to a new industrial sector in China, greatly changes Chinese light olefins supply, and impacts the light olefins market worldwide. Professor Liu also developed coal-based ethanol production technology, via carbonylation of dimethylether and further hydrogenation, and finished its commercialization by construction of a world’s first plant (100KTA) in 2017, which demonstrates a new way for the clean utilization of coal. Up to now, eight DMTE units have been licensed with the ethanol production capacity of 2.25 Mt/a. As DMTE technology can turn the relatively abundant coal resources not food into ethanol, it can safeguard China’s food supply while reduce air pollution.
Prof. Liu has published more than 430 research papers and got 600 authorized patents or more. He also received many awards in his scientific career, including The First Class of the National Technological Invention Awards (2014), The First Class of the National Scientific and Technological Progress Award (2017), Chinese Catalytic Achievement Award (2017), AIChE Professional Achievement Award for Innovations in Green Process Engineering (2018), Highest Science and Technology Awards of Liaoning Province (2019), etc.
Supported by:
National Natural Science Foundation of China(21991092);National Natural Science Foundation of China(21991090);National Natural Science Foundation of China(22072148);National Natural Science Foundation of China(21703239);National Natural Science Foundation of China(22002157);The Innovation Research Foundation of Dalian Institute of Chemical Physics(DICP I202121);The National Natural Science Foundation of Liaoning Province(2022-MS-029);The Key Research Program of Frontier Sciences, Chinese Academy of Sciences(QYZDY-SSW-SC024)

Abstract

Abstract:

Formaldehyde (HCHO), generating from hydrogen transfer (HT) of reactant, is significant for autocatalysis initiation and deactivation in methanol-to-olefins (MTO), but hitherto, its evolution throughout the reaction has not been thoroughly revealed. Herein, by the established colorimetric analysis method, HCHO in the MTO and dimethyl ether (DME)-to-olefins (DTO) reactions over SAPO-34 was in situ quantitatively monitored, where HCHO was detected in slight and conspicuous amounts at initial and deactivation stages with semi-conversion, also when co-fed with water or high-pressure H2. We reveal the weak HT ability of DME relative to methanol, which enables prominent olefins-based cycle and suppresses reactant-induced HT and deactivation in DTO (which is critical for MTO). A complete dynamic reaction network is disclosed, constituting two simultaneous and interplaying pathways: the main reactions for olefin generation as the open-line and HT reactions as the hidden-line. Especially, co-feeding high-pressure H2 with DME capacitating a long-term and highly efficient operation of DTO by modulating the dynamic reaction network to a more moderate autocatalysis evolution, has great potential in industry application.

Key words: Methanol-to-Olefins, Dimethyl ether, Hydrogen transfer, Formaldehyde, Deactivation

Shanfan Lin, Yuchun Zhi, Wenna Zhang, Xiaoshuai Yuan, Chengwei Zhang, Mao Ye, Shutao Xu, Yingxu Wei, Zhongmin Liu. Hydrogen transfer reaction contributes to the dynamic evolution of zeolite-catalyzed methanol and dimethyl ether conversions: Insight into formaldehyde[J]. Chinese Journal of Catalysis, 2023, 46: 11-27.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(22)64194-9

https://www.cjcatal.com/EN/Y2023/V46/I3/11

Figures/Tables 11

Scheme 1. Reaction pathways of HCHO generation and HT reactions involving methanol, DME, and alkenes.

Fig. 1. Conversion and methane selectivity (a), product distribution (b), and colorimetric determination of HCHO concentration (c) versus time on stream for MTO reaction over SAPO-34 at 623 K with a methanol WHSV of 2.0 h?1; (d) Operando DRIFT spectra recorded during methanol conversion on SAPO-34 at 623 K from 0 to 60 min.

Scheme 2. Chromogenic reaction for HCHO detection [42]. HCHO condenses with 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (AHMT, compound I) under alkaline conditions to form compound II, which are then oxidized by potassium periodate to purple-red 6-mercapto-5- triazole (4,3-b)-S-tetrazine (compound III).

Fig. 2. Optimized transition states structures and free energies barriers (ΔG?) of HT reactions over SAPO-34 at 623 K.

Fig. 3. The proposed dynamic reaction network of methanol to hydrocarbon process with hydrogen transfer reactions as hidden line.

Fig. 4. Conversion and methane selectivity (a), product selectivity (b) and colorimetric determination of HCHO concentration (c) versus time on stream for DTO reaction over SAPO-34 at 623 K with a DME WHSV of 1.4 h?1, achieving the same CH2-based WHSV of 6.2 × 10?3 molCH2 h?1 gcat?1 as MTO in Fig. 1(a). (d) Operando DRIFT spectra recorded during DME conversion on SAPO-34 at 623 K from 0 to 60 min.

Fig. 5. The experimental and calculated molar fraction of CH3OH and DME as a function of conversion for MTO (a) and DTO (b) reactions, over SAPO-34 at 623 K. Solid lines: calculated thermodynamic equilibrium molar fraction of CH3OH (orange) and DME (blue) according to the assumption that the CH3OH-DME equilibrium is always established. The detailed calculations are referred to Ref. [19] and described in supporting information and Fig. S12. Dashed lines: experimental molar fraction of CH3OH (orange and yellow) and DME (blue and light blue) in the effluent. Dashed lines with orange and blue ball: MTO and DTO reactions with an initial conversion of 100%, reaction conditions are same as Figs. 1(a) and 4(a). Dashed lines with yellow and light blue circle: MTO and DTO reactions with an initial conversion of 80%, reaction conditions are same as Fig. S8.

Fig. 6. Free energy profiles of propene methylation and HT reactions with methanol (a) and DME (b) over BASs of SAPO-34 at 623 K. Time evolution of 13C content in effluent olefins and retained aromatics formed in the 12C/13C methanol (c) and 12C/13C DME (d) switching experiments over SAPO-34 at 623 K with 12C-methanol/DME feeding for 18 min followed by 0.5, 1.0, and 1.5 min of 13C-methanol/DME feeding, respectively. Reaction conditions are same as Figs. 1(a) and 4(a). (e) Proposed predominant reaction pathways of methanol and DME conversions.

Fig. 7. (a) The principal catalyst deactivation pathways for methanol and DME conversion. (b) The conversion with time on stream for MTO and DTO reactions over SAPO-34 at 623 K. Points: experimental results, reaction conditions are same as Figs. 1(a) and 4(a); Solid lines: the fitted lines according to the deactivation model (Eqs. (1)?(4)).

Fig. 8. Cofeeding H2O in MTO reaction. Conversion (a,d) and colorimetric determination of HCHO concentration (b,c,e,f) versus time on stream for CH3OH-N2 and CH3OH-H2O cofeeding reactions over SAPO-34 at 723 K (a?c) and 548 K (d?f) with a methanol WHSV of 2.0 h?1. The molecular molar ratio of methanol to water is 1:9 for reaction at 723 K, 1:1 and 1:3 for reactions at 548 K.

Fig. 9. Cofeeding high-pressure H2 in MTO and DTO reaction. Conversion (a) and colorimetric determination of HCHO concentration (b-d) versus time on stream for CH3OH-N2 (molecular molar ratio 1:7), CH3OH-H2 (1:7) and DME-N2-H2 (0.5:0.5:7) cofeeding reactions over SAPO-34 at 723 K under 2 MPa. Reaction conditions: methanol WHSV is 4.0 h?1, DME was fed with equimolar carbon amounts of methanol, GHSV is 11206.4 h?1.

References

[1]	P. Tian, Y. Wei, M. Ye, Z. Liu, ACS Catal., 2015, 5, 1922-1938.
[2]	S. Xu, Y. Zhi, J. Han, W. Zhang, X. Wu, T. Sun, Y. Wei, Z. Liu, Adv. Catal., 2017, 61, 37-122.
[3]	I. Yarulina, A. D. Chowdhury, F. Meirer, B. M. Weckhuysen, J. Gascon, Nat. Catal., 2018, 1, 398-411.
[4]	S. Lin, Y. Zhi, W. Chen, H. Li, W. Zhang, C. Lou, X. Wu, S. Zeng, S. Xu, J. Xiao, A. Zheng, Y. Wei, Z. Liu, J. Am. Chem. Soc., 2021, 143, 12038-12052.
[5]	S. Müller, Y. Liu, F. M. Kirchberger, M. Tonigold, M. Sanchez-Sanchez, J. A. Lercher, J. Am. Chem. Soc., 2016, 138, 15994-16003.
[6]	S. Ilias, A. Bhan, ACS Catal., 2013, 3, 18-31.
[7]	X. Sun, S. Mueller, Y. Liu, H. Shi, G. L. Haller, M. Sanchez-Sanchez, A. C. van Veen, J. A. Lercher, J. Catal., 2014, 317, 185-197.
[8]	Y. Liu, F. M. Kirchberger, S. Müller, M. Eder, M. Tonigold, M. Sanchez-Sanchez, J. A. Lercher, Nat. Commun., 2019, 10, 1462.
[9]	S. Müller, Y. Liu, M. Vishnuvarthan, X. Sun, A. C. van Veen, G. L. Haller, M. Sanchez-Sanchez, J. A. Lercher, J. Catal., 2015, 325, 48-59.
[10]	G. J. Hutchings, F. Gottschalk, R. Hunter, Ind. Eng. Chem. Res., 1987, 26, 635-637.
[11]	G. J. Hutchings, F. Gottschalk, M. V. M. Hall, R. Hunter, J. Chem. Soc., Faraday Trans. 1, 1987, 83, 571-583.
[12]	L. Kubelková, J. Nováková, P. Jírů, Stud. Surf. Sci. Catal., 1984, 18, 217-224.
[13]	J. Nováková, L. Kubelková, Z. Dolejšek, J. Catal., 1987, 108, 208-213.
[14]	P. N. Plessow, F. Studt, ACS Catal., 2017, 7, 7987-7994.
[15]	Y. Liu, S. Müller, D. Berger, J. Jelic, K. Reuter, M. Tonigold, M. Sanchez-Sanchez, J. A. Lercher, Angew. Chem. Int. Ed., 2016, 55, 5723-5726.
[16]	Z. Wei, Y.-Y. Chen, J. Li, P. Wang, B. Jing, Y. He, M. Dong, H. Jiao, Z. Qin, J. Wang, W. Fan, Catal. Sci. Technol., 2016, 6, 5526-5533.
[17]	F. M. Kirchberger, Y. Liu, P. N. Plessow, M. Tonigold, F. Studt, M. Sanchez-Sanchez, J. A. Lercher, Proc. Natl. Acad. Sci. U. S. A., 2022, 119, e2103840119.
[18]	J. S. Martinez-Espin, K. De Wispelaere, M. Westgård Erichsen, S. Svelle, T. V. W. Janssens, V. Van Speybroeck, P. Beato, U. Olsbye, J. Catal., 2017, 349, 136-148.
[19]	J. S. Martinez-Espin, M. Mortén, T. V. W. Janssens, S. Svelle, P. Beato, U. Olsbye, Catal. Sci. Technol., 2017, 7, 2700-2716.
[20]	J. S. Martínez-Espín, K. De Wispelaere, T. V. W. Janssens, S. Svelle, K. P. Lillerud, P. Beato, V. Van Speybroeck, U. Olsbye, ACS Catal., 2017, 7, 5773-5780.
[21]	N. Tajima, T. Tsuneda, F. Toyama, K. Hirao, J. Am. Chem. Soc., 1998, 120, 8222-8229.
[22]	A. Comas-Vives, M. Valla, C. Copéret, P. Sautet, ACS Cent. Sci., 2015, 1, 313-319.
[23]	Y. Chu, X. Yi, C. Li, X. Sun, A. Zheng, Chem. Sci., 2018, 9, 6470-6479.
[24]	C. Wang, Y. Chu, J. Xu, Q. Wang, G. Qi, P. Gao, X. Zhou, F. Deng, Angew. Chem. Int. Ed., 2018, 57, 10197-10201.
[25]	L. Yang, T. Yan, C. Wang, W. Dai, G. Wu, M. Hunger, W. Fan, Z. Xie, N. Guan, L. Li, ACS Catal., 2019, 9, 6491-6501.
[26]	A. Hwang, A. Bhan, Acc. Chem. Res., 2019, 52, 2647-2656.
[27]	B. L. Foley, B. A. Johnson, A. Bhan, ACS Catal., 2021, 11, 3628-3637.
[28]	P. Bollini, T. T. Chen, M. Neurock, A. Bhan, Catal. Sci. Technol., 2019, 9, 4374-4383.
[29]	S. S. Arora, D. L. S. Nieskens, A. Malek, A. Bhan, Nat. Catal., 2018, 1, 666-672.
[30]	S. S. Arora, Z. Shi, A. Bhan, ACS Catal., 2019, 9, 6407-6414.
[31]	A. Hwang, A. Bhan, ACS Catal., 2017, 7, 4417-4422.
[32]	J. G. Dojahn, W. E. Wentworth, S. D. Stearns, J. Chromatogr. Sci., 2001, 39, 54-58.
[33]	J. Nováková, L. Kubelkova, K. Habersberger, Z. Dolejšek, J. Chem. Soc., Faraday Trans. 1, 1984, 80, 1457-1465.
[34]	O. Dewaele, V. L. Geers, G. F. Froment, G. B. Marin, Chem. Eng. Sci., 1999, 54, 4385-4395.
[35]	X. Wu, S. Xu, W. Zhang, J. Huang, J. Li, B. Yu, Y. Wei, Z. Liu, Angew. Chem. Int. Ed., 2017, 56, 9039-9043.
[36]	W. Wen, S. Yu, C. Zhou, H. Ma, Z. Zhou, C. Cao, J. Yang, M. Xu, F. Qi, G. Zhang, Y. Pan, Angew. Chem. Int. Ed., 2020, 59, 4873-4878.
[37]	J. Chen, J. Li, Y. Wei, C. Yuan, B. Li, S. Xu, Y. Zhou, J. Wang, M. Zhang, Z. Liu, Catal. Commun., 2014, 46, 36-40.
[38]	M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, G. Scalmani, V. Barone, B. Mennucci, G. A. Petersson, H. Nakatsuji, M. Caricato, X. Li, H. P. Hratchian, A. F. Izmaylov, J. Bloino, G. Zheng, J. L. Sonnenberg, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Naka, T. Vreven, J. A. Montgomery, J. E. Peralta, F. Ogliaro, M. Bearpark, J. J. Heyd, E. Brothers, K. N. Kudin, V. N. Staroverov, R. Kobayashi, J. Normand, K. Raghavachari, A. Rendell, C. J. Burant, S. S. Iyengar, J. Tomasi, M. Cossi, N. Rega, J. M. Millam, M. Klene, J. E. Knox, J. B. Cross, V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, R. L. Martin, K. Morokuma, V. G. Zakrzewski, G. A. Voth, P. Salvador, J. J. Dannenberg, S. Dapprich, A. D. Daniels, O. Farkas, J. B. Foresman, J. V.Ortiz, J. Cioslowski, D. J. Fox, Gaussian 09 Revision B,. 01 Gaussian, Inc.: Wallingford, CT, 2010.
[39]	P. J. O'Malley, J. Dwyer, Zeolites, 1988, 8, 317-321.
[40]	J.-D. Chai, M. Head-Gordon, Phys. Chem. Chem. Phys., 2008, 10, 6615-6620.
[41]	U. Olsbye, S. Svelle, M. Bjørgen, P. Beato, T. V. W. Janssens, F. Joensen, S. Bordiga, K. P. Lillerud, Angew. Chem. Int. Ed., 2012, 51, 5810-5831.
[42]	GB/T 16129-1995.
[43]	S. M. Campbell, X.-Z. Jiang, R. F. Howe, Microporous Mesoporous Mater., 1999, 29, 91-108.
[44]	T. R. Forester, R. F. Howe, J. Am. Chem. Soc., 1987, 109, 5076-5082.
[45]	S. A. Zubkov, L. M. Kustov, V. B. Kazansky, I. Girnus, R. Fricke, J. Chem. Soc., Faraday Trans., 1991, 87, 897-900.
[46]	X. Wu, S. Xu, Y. Wei, W. Zhang, J. Huang, S. Xu, Y. He, S. Lin, T. Sun, Z. Liu, ACS Catal., 2018, 8, 7356-7361.
[47]	I. B. Minova, S. K. Matam, A. Greenaway, C. R. A. Catlow, M. D. Frogley, G. Cinque, P. A. Wright, R. F. Howe, ACS Catal., 2019, 9, 6564-6570.
[48]	J. D. Mosley, J. W. Young, J. Agarwal, H. F. Schaefer Iii, P. V. R. Schleyer, M. A. Duncan, Angew. Chem. Int. Ed., 2014, 53, 5888-5891.
[49]	S. Shao, H. Zhang, R. Xiao, X. Li, Y. Cai, J. Anal. Appl. Pyrolysis, 2017, 127, 258-268.
[50]	S. R. Blaszkowski, R. A. van Santen, J. Am. Chem. Soc., 1997, 119, 5020-5027.
[51]	J. Li, Z. Wei, Y. Chen, B. Jing, Y. He, M. Dong, H. Jiao, X. Li, Z. Qin, J. Wang, W. Fan, J. Catal., 2014, 317, 277-283.
[52]	D. Lesthaeghe, V. Van Speybroeck, G. B. Marin, M. Waroquier, Angew. Chem. Int. Ed., 2006, 45, 1714-1719.
[53]	S. Lin, Y. Zhi, Z. Liu, J. Yuan, W. Liu, W. Zhang, Z. Xu, A. Zheng, Y. Wei, Z. Liu, Natl. Sci. Rev., 2022, 9, nwac151.
[54]	C. Peng, H. Wang, P. Hu, Phys. Chem. Chem. Phys., 2016, 18, 14495-14502.
[55]	W. Zhang, Y. Zhi, J. Huang, X. Wu, S. Zeng, S. Xu, A. Zheng, Y. Wei, Z. Liu, ACS Catal., 2019, 9, 7373-7379.
[56]	B. P. C. Hereijgers, F. Bleken, M. H. Nilsen, S. Svelle, K.-P. Lillerud, M. Bjørgen, B. M. Weckhuysen, U. Olsbye, J. Catal., 2009, 264, 77-87.
[57]	S. Svelle, F. Joensen, J. Nerlov, U. Olsbye, K.-P. Lillerud, S. Kolboe, M. Bjørgen, J. Am. Chem. Soc., 2006, 128, 14770-14771.
[58]	M. Bjørgen, S. Svelle, F. Joensen, J. Nerlov, S. Kolboe, F. Bonino, L. Palumbo, S. Bordiga, U. Olsbye, J. Catal., 2007, 249, 195-207.
[59]	K. De Wispelaere, C. S. Wondergem, B. Ensing, K. Hemelsoet, E. J. Meijer, B. M. Weckhuysen, V. Van Speybroeck, J. Ruiz-Martı́nez, ACS Catal., 2016, 6, 1991-2002.
[60]	K. Stanciakova, B. M. Weckhuysen, Trends Chem., 2021, 3, 456-468.
[61]	P. N. Plessow, F. Studt, Catal. Sci. Technol., 2018, 8, 4420-4429.
[62]	S. Svelle, B. Arstad, S. Kolboe, O. Swang, J. Phys. Chem. B, 2003, 107, 9281-9289.
[63]	S. Svelle, C. Tuma, X. Rozanska, T. Kerber, J. Sauer, J. Am. Chem. Soc., 2009, 131, 816-825.
[64]	V. Van Speybroeck, J. Van der Mynsbrugge, M. Vandichel, K. Hemelsoet, D. Lesthaeghe, A. Ghysels, G. B. Marin, M. Waroquier, J. Am. Chem. Soc., 2011, 133, 888-899.
[65]	S. Svelle, M. Visur, U. Olsbye, Saepurahman, M. Bjørgen, Top. Catal., 2011, 54, 897-906.
[66]	J. Van der Mynsbrugge, S. L. C. Moors, K. De Wispelaere, V. Van Speybroeck, ChemCatChem, 2014, 6, 1906-1918.
[67]	R. Y. Brogaard, R. Henry, Y. Schuurman, A. J. Medford, P. G. Moses, P. Beato, S. Svelle, J. K. Nørskov, U. Olsbye, J. Catal., 2014, 314, 159-169.
[68]	B. Arstad, S. Kolboe, O. Swang, J. Phys. Chem. B, 2002, 106, 12722-12726.
[69]	U. Olsbye, S. Svelle, K. P. Lillerud, Z. H. Wei, Y. Y. Chen, J. F. Li, J. G. Wang, W. B. Fan, Chem. Soc. Rev., 2015, 44, 7155-7176.
[70]	J. F. Haw, D. M. Marcus, Top. Catal., 2005, 34, 41-48.
[71]	S. V. Konnov, V. S. Pavlov, P. A. Kots, V. B. Zaytsev, I. I. Ivanova, Catal. Sci. Technol., 2018, 8, 1564-1577.
[72]	A. J. Marchi, G. F. Froment, Appl. Catal. A, 1993, 94, 91-106.
[73]	A. J. Marchi, G. F. Froment, Appl. Catal., 1991, 71, 139-152.
[74]	H. Wang, Y. Hou, W. Sun, Q. Hu, H. Xiong, T. Wang, B. Yan, W. Qian, ACS Catal., 2020, 10, 5288-5298.
[75]	X. Zhao, J. Li, P. Tian, L. Wang, X. Li, S. Lin, X. Guo, Z. Liu, ACS Catal., 2019, 9, 3017-3025.
[76]	M. DeLuca, C. Janes, D. Hibbitts, ACS Catal., 2020, 10, 4593-4607.
[77]	X. Wu, R. G. Anthony, Appl. Catal. A, 2001, 218, 241-250.
[78]	Z. Liu, Y. Ni, X. Fang, W. Zhu, Z. Liu, J. Energy Chem., 2021, 58, 573-576.
[79]	Y. Ni, Z. Liu, P. Tian, Z. Chen, Y. Fu, W. Zhu, Z. Liu, J. Energy Chem., 2022, 66, 190.
[80]	Y. Ni, Y. Liu, Z. Chen, M. Yang, H. Liu, Y. He, Y. Fu, W. Zhu, Z. Liu, ACS Catal., 2019, 9, 1026-1032.

Hydrogen transfer reaction contributes to the dynamic evolution of zeolite-catalyzed methanol and dimethyl ether conversions: Insight into formaldehyde

RichHTML

PDF (PC)

Knowledge

Supporting Information

Abstract

Cite this article

share this article

share this article

Figures/Tables 11

References

Related Articles 15

Recommended Articles

Metrics

[1]	Yongbiao Hua, Kumar Vikrant, Ki-Hyun Kim, Philippe M. Heynderickx, Danil W. Boukhvalov. Alkali-modified copper manganite spinel for room temperature catalytic oxidation of formaldehyde in air [J]. Chinese Journal of Catalysis, 2024, 60(5): 337-350.
[2]	Wangyan Gou, Yichen Wang, Mingkai Zhang, Xiaohe Tan, Yuanyuan Ma, Yongquan Qu. A review on fundamentals for designing stable ruthenium-based catalysts for the hydrogen and oxygen evolution reactions [J]. Chinese Journal of Catalysis, 2024, 60(5): 68-106.
[3]	Dae-Hwan Lim, Aadil Bathla, Hassan Anwer, Sherif A. Younis, Danil W. Boukhvalov, Ki-Hyun Kim. The effects of nitrogen-doping on photocatalytic mineralization of TiO₂ nanocatalyst against formaldehyde in ambient air [J]. Chinese Journal of Catalysis, 2024, 59(4): 303-323.
[4]	Enara Fernandez, Laura Santamaria, Irati García, Maider Amutio, Maite Artetxe, Gartzen Lopez, Javier Bilbao, Martin Olazar. Elucidating coke formation and evolution in the catalytic steam reforming of biomass pyrolysis volatiles at different fixed bed locations [J]. Chinese Journal of Catalysis, 2023, 48(5): 101-116.
[5]	Ye Wang, Jingfeng Han, Nan Wang, Bing Li, Miao Yang, Yimo Wu, Zixiao Jiang, Yingxu Wei, Peng Tian, Zhongmin Liu. Conversion of methanol to propylene over SAPO-14: Reaction mechanism and deactivation [J]. Chinese Journal of Catalysis, 2022, 43(8): 2259-2269.
[6]	Mengru Wang, Yi Wang, Xiaoling Mou, Ronghe Lin, Yunjie Ding. Design strategies and structure-performance relationships of heterogeneous catalysts for selective hydrogenation of 1,3-butadiene [J]. Chinese Journal of Catalysis, 2022, 43(4): 1017-1041.
[7]	Hongwei Lv, Wenxin Guo, Min Chen, Huang Zhou, Yuen Wu. Rational construction of thermally stable single atom catalysts: From atomic structure to practical applications [J]. Chinese Journal of Catalysis, 2022, 43(1): 71-91.
[8]	Sen Wang, Zhikai Li, Zhangfeng Qin, Mei Dong, Junfen Li, Weibin Fan, Jianguo Wang. Catalytic roles of the acid sites in different pore channels of H-ZSM-5 zeolite for methanol-to-olefins conversion [J]. Chinese Journal of Catalysis, 2021, 42(7): 1126-1136.
[9]	Renyang Zheng, Zaiku Xie. Full life cycle characterization strategies for spatiotemporal evolution of heterogeneous catalysts [J]. Chinese Journal of Catalysis, 2021, 42(12): 2141-2148.
[10]	Nian Lei, Zhili Miao, Fei Liu, Hua Wang, Xiaoli Pan, Aiqin Wang, Tao Zhang. Understanding the deactivation behavior of Pt/WO₃/Al₂O₃ catalyst in the glycerol hydrogenolysis reaction [J]. Chinese Journal of Catalysis, 2020, 41(8): 1261-1267.
[11]	Jibin Zhou, Jianping Zhao, Jinling Zhang, Tao Zhang, Mao Ye, Zhongmin Liu. Regeneration of catalysts deactivated by coke deposition: A review [J]. Chinese Journal of Catalysis, 2020, 41(7): 1048-1061.
[12]	Jifeng Pang, Mingyuan Zheng, Zhinuo Wang, Shimin Liu, Xinsheng Li, Xianquan Li, Junhu Wang, Tao Zhang. Catalytic upgrading of ethanol to butanol over a binary catalytic system of FeNiO_x and LiOH [J]. Chinese Journal of Catalysis, 2020, 41(4): 672-678.
[13]	Junhui Zhou, Guanlan Liu, Quanguo Jiang, Weina Zhao, Zhimin Ao, Taicheng An. Density functional theory calculations on single atomic catalysis: Ti-decorated Ti₃C₂O₂ monolayer (MXene) for HCHO oxidation [J]. Chinese Journal of Catalysis, 2020, 41(10): 1633-1644.
[14]	Dongni Yu, Weili Dai, Guangjun Wu, Naijia Guan, Landong Li. Stabilizing copper species using zeolite for ethanol catalytic dehydrogenation to acetaldehyde [J]. Chinese Journal of Catalysis, 2019, 40(9): 1375-1384.
[15]	Na Zhao, Ye Tian, Lifu Zhang, Qingpeng Cheng, Shuaishuai Lyu, Tong Ding, Zhenpeng Hu, Xinbin Ma, Xingang Li. Spacial hindrance induced recovery of over-poisoned active acid sites in pyridine-modified H-mordenite for dimethyl ether carbonylation [J]. Chinese Journal of Catalysis, 2019, 40(6): 895-904.