Chinese Journal of Catalysis ›› 2023, Vol. 48: 235-246.DOI: 10.1016/S1872-2067(23)64409-2
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Jinxing Mia,1, Xiaoping Chenb,1, Yajun Dinga, Liangzhu Zhanga, Jun Mac, Hui Kangc, Xianhong Wua, Yuefeng Liuc, Jianjun Chenb,*(), Zhong-Shuai Wua,*(
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Received:
2022-01-03
Accepted:
2022-02-08
Online:
2023-05-18
Published:
2023-04-20
Contact:
* E-mail: About author:
First author contact:1Contributed equally to this work.
Supported by:
Jinxing Mi, Xiaoping Chen, Yajun Ding, Liangzhu Zhang, Jun Ma, Hui Kang, Xianhong Wu, Yuefeng Liu, Jianjun Chen, Zhong-Shuai Wu. Activation of partial metal sites in high-entropy oxides for enhancing thermal and electrochemical catalysis[J]. Chinese Journal of Catalysis, 2023, 48: 235-246.
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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(23)64409-2
Fig. 1. XRD patterns (a), N2 adsorption-desorption isotherms (inset: pore size distribution profiles) (b), H2-TPR profiles (c), and Raman spectra (d) of CuCoNiZnAl, CuCoNiZnAl-T, and CuCoNiZnAl-T-NaOH.
Fig. 2. SEM images of CuCoNiZnAl (a), CuCoNiZnAl-T (b), and CuCoNiZnAl-T-NaOH (c). HRTEM images of CuCoNiZnAl (d), CuCoNiZnAl-T (e), and CuCoNiZnAl-T-NaOH (f). STEM image (g) and Cu (h), Co (i), Ni (j), Zn (k), and Al (l) elemental distributions in CuCoNiZnAl-T-NaOH examined at nanometer scale using STEM-EDS.
Fig. 3. O 1s XPS spectra (a) and He-TPD profiles (b) of CuCoNiZnAl, CuCoNiZnAl-T, and CuCoNiZnAl-T-NaOH. (c) Schematic diagram illustrating the physical-chemical property evolution from CuCoNiZnAl to CuCoNiZnAl-T and then to CuCoNiZnAl-T-NaOH.
Fig. 4. (a) Rates for CO2 hydrogenation. (b) CO conversion for CO oxidation. (c) Initial discharge-charge profiles at a current density of 200 mA/g for an Li-O2 battery using CuCoNiZnAl, CuCoNiZnAl-T, and CuCoNiZnAl-T-NaOH as cathodes. (d) Typical discharge-charge profiles of the CuCoNiZnAl-T-NaOH cathode under a voltage range of 2.0-4.5 V at 200 mA/g. (e) Cycling performance of CuCoNiZnAl-T-NaOH cathode under a capacity limit of 500 mA h/g at 200 mA/g.
Fig. 5. In-situ Co 2p (a), Ni 2p (b), and O 1s (c) XPS spectra of CuCoNiZnAl, and Co 2p (d), Ni 2p (e), and O 1s (f) XPS spectra of CuCoNiZnAl-T in contact with 0.1 mbar H2 at 400 °C, 0.1 mbar CO2 at 350 °C, and 0.4 mbar of CO2 (0.1 mbar) + H2 (0.3 mbar) at 350 °C.
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