Chinese Journal of Catalysis ›› 2023, Vol. 50: 109-125.DOI: 10.1016/S1872-2067(23)64452-3
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Yuannan Wang,1, Lina Wang,1, Kexin Zhang, Jingyao Xu, Qiannan Wu, Zhoubing Xie, Wei An, Xiao Liang(), Xiaoxin Zou*()
Received:
2023-03-28
Accepted:
2023-05-08
Online:
2023-07-18
Published:
2023-07-25
Contact:
*E-mail: About author:
Xiao Liang (State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University) received her PhD in inorganic chemistry from Jilin University in 2021. She is currently a postdoctoral researcher at State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University. Her research interests focus on the design of water splitting electrocatalysts, especially the acidic water oxidation electrocatalysts in proton exchange membrane water electrolysis application.1 Contributed equally to this work.
Supported by:
Yuannan Wang, Lina Wang, Kexin Zhang, Jingyao Xu, Qiannan Wu, Zhoubing Xie, Wei An, Xiao Liang, Xiaoxin Zou. Electrocatalytic water splitting over perovskite oxide catalysts[J]. Chinese Journal of Catalysis, 2023, 50: 109-125.
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URL: https://www.cjcatal.com/EN/10.1016/S1872-2067(23)64452-3
Fig. 5. (a) Volcanic plot of the OER overpotential for perovskite oxides. (a) Reprinted with permission from Ref. [82]. Copyright 2011, Wiley-VCH. (b) Diagram of OER overpotential versus eg occupancy of perovskite oxides. (b) Reprinted with permission from Ref. [93]. Copyright 2017, Elsevier Inc. (c) Comparison of OER activity and Tafel slope of LCO films. (d) LCO films with different spin states of Co ions and their OER catalytic activities. (c,d) Reprinted with permission from Ref. [99]. Copyright 2017, Elsevier Inc. (e) Plots of mass activity versus eg electron and specific activity comparison between bulk and 80 nm LCO. (e) Reprinted with permission from Ref. [100]. Copyright 2016, Springer Nature.
Fig. 6. (a) Diagram of OER overpotential versus O p-band relative to EF of perovskite oxides. (a) Reprinted with permission from Ref. [69]. Copyright 2013, Springer Nature. (b) Molecular orbital diagrams of MnO6 and FeO6. (b) Reprinted with permission from Ref. [105]. Copyright 2015, Springer Nature. (c) Schematics of the calculations of electron-transfer energy, hydroxide affinity, and charge-transfer energy (left), and the trend plot of perovskite oxides band positions in relation to OER activity (right). (d) Illustrations of Tafel slope versus electron transfer, pH of zero charge versus hydroxide, and adsorbate binding energy ΔGO*-OH* versus charge-transfer energy. (e) Relationships of charge-transfer energy to hydroxide affinity, adsorbate binding, and electron transfer. (c-e) Reprinted with permission from Ref. [107]. Copyright 2017, The Royal Society of Chemistry.
Fig. 9. (a) Theoretical overpotential volcano plot of the 3C-SrIrO3 system and models of IrOx on the 3C-SrIrO3 surface. Models are listed in the order of IrO2 termination of SrIrO3 (001), replacement of the top two layers of SrIrO3 with anatase IrO2 (001), limiting case of pure anatase IrO2 (001), square-coordinated IrO4 planes anchored by SrIrO3 (001), IrO3 film formed via filling the vacant (100) planes with oxygen, IrO3 obtained by further removing the Sr of the third layer, and rutile IrO2 (110). (a) Reprinted with permission from Ref. [128]. Copyright 2016, American Association for the Advancement of Science. (b) Model of IrOx on 9R-BaIrO3 surface. (c) HAADF-STEM image of the 9R-BaIrO3 and surface IrOx amorphous particles. (b,c) Reprinted with permission from Ref. [129]. Copyright 2021, American Chemical Society. (d) Optical images of the solutions after acid corrosion test of double perovskite. (e) Schematic of structure evolution on the surface of double perovskite containing unstable B' cations. (d,e) Reprinted with permission from Ref. [132]. Copyright 2022, Elsevier Inc.
Fig. 10. (a) Structural illustration of 6H-SrIrO3. (b) Comparison of the percentages of Sr leached by 6H-SrIrO3 and 3C-SrIrO3 after the OER stability test. (a,b) Reprinted with permission from Ref. [133]. Copyright 2018, Springer Nature. (c) Preparation process of HION. (d) Schematic illustration of the AEM, involving surface hydroxyl groups of 18O-labeled HION to produce 34O2 products. (c,d) Reprinted with permission from Ref. [134]. Copyright 2022, American Chemical Society. (e) Structural model of several atomic layers of anatase phase TiO2-IrO2 solid solution on the SrTi(Ir)O3 surface. (f) Theoretical overpotential volcano plot of anatase phase TiO2-IrO2 solid solution and certain other transition metal oxides. (e,f) Reprinted with permission from Ref. [58]. Copyright 2020, Wiley-VCH.
Fig. 12. In situ XAS spectra of Co K-edge XANES (a) and Co K-edge FT-EXAFS (b) for Co0.8Fe0.2O3-δ at 1.47-1.52 V vs. RHE (c) Diagram illustrating the generation of OER active phase on the surface. (a-c) Reprinted with permission from Ref. [143]. Copyright 2018, The Royal Society of Chemistry In situ Raman spectra of La1-xCexNiO3 (x = 0) (d) and La1-xCexNiO3 (x = 0.1) (e) with potential from 1 to 1.7 V vs. RHE. (f) Schematic of Ce doping, promoting structural evolution of perovskite and generation of active phase NiOOH. (d-f) Reprinted with permission from Ref. [146]. Copyright 2021, John Wiley & Sons, Ltd.
Fig. 13. (a) Diagram illustrating the LOM of Fe′-LS′C. (b) 18O labeled tof-SIMS characterizations of LSC, LSCF, and Fe′-LS′C. (c) 18O16O/16O2 product ratios of LSC, LSCF, and Fe′-LS′C obtained by DEMS. Reprinted with permission from Ref. [118]. Copyright 2021, The Royal Society of Chemistry.
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