]*>","")" /> 氧化锰八面体分子筛纳米棒的合成及其催化甲醛低温氧化性能

催化学报 ›› 2006, Vol. 27 ›› Issue (2): 97-99.

• 研究快讯 •    下一篇

氧化锰八面体分子筛纳米棒的合成及其催化甲醛低温氧化性能

唐幸福,黄秀敏,邵建军,刘俊龙,李永刚,徐奕德,申文杰   

  1. 中国科学院大连化学物理研究所催化基础国家重点实验室, 辽宁大连 116023
  • 收稿日期:2006-02-25 出版日期:2006-02-25 发布日期:1985-02-26

  • Received:2006-02-25 Online:2006-02-25 Published:1985-02-26

摘要: Uniform manganese oxide octahedral molecular sieve (OMS-2) nanorods were synthesized by adding a small quantity of K2S2O8 to the solution containing MnSO4·H2O and KMnO4, and used for complete oxidation of formaldehyde. According to the results of N2 adsorption and X-ray diffraction, the material is a manganese oxide octahedral molecular sieve with the cryptomelane type structure. TEM observation shows that the diameters of the nanorods range from 15 to 25 nm, and the lengths are 300~400 nm. Complete conversion of HCHO to CO2 and H2O can be achieved at 353 K over OMS-2, and the same conversion is obtained at 373 K on the MnOx powder under the same conditions, which demonstrates that the catalytic activity is closely related to the morphology of the catalysts.

关键词: 氧化锰, 八面体分子筛, 甲醛, 氧化